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1605-53-4

1605-53-4 Structure

1605-53-4 Structure
IdentificationMore
[Name]

DIETHYLPHENYLPHOSPHINE
[CAS]

1605-53-4
[Synonyms]

DIETHYLPHENYLPHOSPHINE
Diethylphenylphosphene
Phosphine, diethylphenyl-
Diethylphenylphosphine ,96%
Phenyldiethylphosphine
[EINECS(EC#)]

216-516-6
[Molecular Formula]

C10H15P
[MDL Number]

MFCD00015172
[Molecular Weight]

166.2
[MOL File]

1605-53-4.mol
Chemical PropertiesBack Directory
[Melting point ]

45 °C
[Boiling point ]

120-121 °C/29 mmHg (lit.)
[density ]

0.954 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.546(lit.)
[Fp ]

185 °F
[form ]

Liquid
[color ]

Colorless to Light yellow
[Specific Gravity]

0.954
[Water Solubility ]

Not miscible or difficult to mix in water.
[Sensitive ]

Air & Moisture Sensitive
[Detection Methods]

GC
[BRN ]

742484
[InChI]

InChI=1S/C10H15P/c1-3-11(4-2)10-8-6-5-7-9-10/h5-9H,3-4H2,1-2H3
[InChIKey]

LVTCZSBUROAWTE-UHFFFAOYSA-N
[SMILES]

P(CC)(CC)C1=CC=CC=C1
[CAS DataBase Reference]

1605-53-4(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S17:Keep away from combustible material .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN3278
[WGK Germany ]

3
[F ]

10
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29319090
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Diethyl ether-->Nitrogen-->Magnesium-->Bromoethane-->Dichlorophenylphosphine
Hazard InformationBack Directory
[Chemical Properties]

Colorless liquid
[Uses]

Diethylphenylphosphine is used as a catalyst for selective cross-dimerization, carboxyl migration reactions, selective hydrogenation, asymmetric induction by chiral diphosphines in ring contraction.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
Spectrum DetailBack Directory
[Spectrum Detail]

DIETHYLPHENYLPHOSPHINE(1605-53-4)MS
DIETHYLPHENYLPHOSPHINE(1605-53-4)1HNMR
DIETHYLPHENYLPHOSPHINE(1605-53-4)13CNMR
DIETHYLPHENYLPHOSPHINE(1605-53-4)IR1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Diethylphenylphosphine, 97%(1605-53-4)
[Sigma Aldrich]

1605-53-4(sigmaaldrich)
[TCI AMERICA]

Diethylphenylphosphine,>96.0%(GC)(1605-53-4)
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