ChemicalBook--->CAS DataBase List--->16567-18-3

16567-18-3

16567-18-3 Structure

16567-18-3 Structure
IdentificationMore
[Name]

8-Bromoquinoline
[CAS]

16567-18-3
[Synonyms]

8-BROMOQUINOLINE
RARECHEM AK ML 0146
8-BROMOQUIOLINE
http://www.ruiyitech.com/detail.phpCAS=578-66-5&class_id=4
8-bromooquinoline
8-Bromoquinoline ,97%
[EINECS(EC#)]

630-629-1
[Molecular Formula]

C9H6BrN
[MDL Number]

MFCD00191859
[Molecular Weight]

208.05
[MOL File]

16567-18-3.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powder
[Melting point ]

58-59 °C
[Boiling point ]

112-113 °C/0.5 mmHg (lit.)
[density ]

1.594 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.672(lit.)
[Fp ]

>230 °F
[storage temp. ]

Refrigerator (+4°C)
[form ]

Liquid After Melting
[pka]

2.33±0.17(Predicted)
[color ]

Clear yellow to yellow-brown
[Specific Gravity]

1.594
[Sensitive ]

Light Sensitive
[Detection Methods]

GC
[InChIKey]

PIWNKSHCLTZKSZ-UHFFFAOYSA-N
[CAS DataBase Reference]

16567-18-3(CAS DataBase Reference)
[NIST Chemistry Reference]

Quinoline, 8-bromo-(16567-18-3)
[Storage Precautions]

Store under nitrogen
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HS Code ]

29334900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sulfuric acid-->Glycerol-->Sodium iodide-->2-Bromoaniline-->Sodium iodide dihydrate
[Preparation Products]

8-Quinolineboronic acid-->METHYLQUINOLINE-8-CARBOXYLATE
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powder
[Uses]

8-Bromoquinoline may be used in the following studies:
  • Synthesis of 8-(dimesitylboryl)quinolone (ambiphilic molecule).
  • Direct synthesis of 5H-pyrido[3,2,1-ij]quinolin-3-one, via palladium catalyzed coupling reaction with acrolein.
  • Preparation of 8-(1-hydroxyethyl)quinolone.
  • Preparation of 8-quinolylcyclopentadienyl metal complexes, via reaction with zincated cyclopentadienyl derivatives of Fe, Mn and Re in the presence of bis(triphenylphosphine)palladium(0).
  • Synthesis of n,n′-biquinolines by a coupling reaction using tris(triphenylphosphine)nickel(0) and a zerovalent pyridine-nickel complex.
[General Description]

8-Bromoquinoline is a quinolone derivative. It is widely employed for the synthesis of dyes, food colors, pharmaceutical reagents, pH indicators and in various industrial processes. Its molecule bears a pyridyl group. It undergoes direct heteroarylation reaction with various heteroaromatic compounds in the presence of a palladium catalyst to afford polyheteroaromatic derivatives.
Spectrum DetailBack Directory
[Spectrum Detail]

8-Bromoquinoline(16567-18-3)IR
8-Bromoquinoline(16567-18-3)FT-IR
8-Bromoquinoline(16567-18-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

8-Bromoquinoline, 96%(16567-18-3)
[Alfa Aesar]

8-Bromoquinoline, 98%(16567-18-3)
[Sigma Aldrich]

16567-18-3(sigmaaldrich)
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