ChemicalBook--->CAS DataBase List--->1667-99-8

1667-99-8

1667-99-8 Structure

1667-99-8 Structure
IdentificationBack Directory
[Name]

Mordant Blue 29
[CAS]

1667-99-8
[Synonyms]

S NO 841
CI 43825
CI NO 43825
Mordantblue
CHROMAZUROL S
ChomeazurolS
S,ChroMeazurol
PolytropeblueB
CHROME AZUROL S
MORDANT BLUE 29
Chrome Cyanine BLA
de ChroMe Azurol S
C.I.Mordant Blue 29
ERIOCHROME AZUROL S
TIMTEC-BB SBB006521
CAS, Chrome azurol S
Chrome Azurol S, pure
Chromium(Metal)Powder99%
Mordant blue 29 (C.I. 43825)
Solochrome Brilliant Blue BS
chrome azurol S (C.I. 43825)
CHROMAZUROL S (C.I. No 43825 )
Chrome Azurol S, Mordant Blue29
Chrome Azurol S, Dye content: approx. 65%
CHROME AZUROL S INDICATOR FOR METAL TITRATION
2,6-DICHLORODIMETHYL-SULFOXY-FUCHSONEDICARBOXYLIC ACID SODIUM SALT
benzoicacid,5-[(3-carboxy-5-methyl-4-oxo-2,5-cyclohexadien-1-ylidene)(2,6-dic
Chrome Azurol S 2,6-Dichlorodimethyl-sulfoxy-fuchsonedicarboxylic Acid Sodium Salt
Benzoicacid,5-[(3-carboxy-5-methyl-4-oxo-2,5-cyclohexadien-1-ylidene)(2,6-dichloro-3-sulfophenyl)methyl]-2-hydroxy-3-methyl-,trisodiumsalt
trisodium 5-[(3-carboxylato-5-methyl-4-oxo-2,5-cyclohexadien-1-ylidene)(2,6-dichloro-3-sulphonatophenyl)methyl]-2-hydroxy-3-methylbenzoate
Benzoic acid, 5-(3-carboxy-5-methyl-4-oxo-2,5-cyclohexadien-1-ylidene)(2,6-dichloro-3-sulfophenyl)methyl-2-hydroxy-3-methyl-, trisodium salt
2,4-Dichloro-3-[(3-sodiooxycarbonyl-4-hydroxy-5-methylphenyl)(3-sodiooxycarbonyl-4-oxo-5-methyl-2,5-cyclohexadienylidene)methyl]benzenesulfonic acid sodium salt
[EINECS(EC#)]

216-787-0
[Molecular Formula]

C23H13Cl2Na3O9S
[MDL Number]

MFCD00001615
[MOL File]

1667-99-8.mol
[Molecular Weight]

605.28
Chemical PropertiesBack Directory
[Appearance]

dark brown powder
[storage temp. ]

room temp
[solubility ]

water: 0.1%
[Colour Index ]

43825
[form ]

Powder
[pka]

pK1:2.45;pK2:4.86;pK3:11.47 (25°C)
[color ]

Dark-brown
[Odor]

Odorless
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[Water Solubility ]

Soluble in water
[ε(extinction coefficient)]

≥9000 at 424-436nm in H2O at 0.03g/L
≥9000 at 424-436nm in H2O
[λmax]

458 nm
[BRN ]

4110655
[Major Application]

diagnostic assay manufacturing
hematology
histology
[InChIKey]

FUIZKNBTOOKONL-NDOZRWCBSA-K
[SMILES]

C(=C1/C=C(C(=O)C(C([O-])=O)=C/1)C)(/C1=CC(=C(O)C(C([O-])=O)=C1)C)\C1C(Cl)=CC=C(S([O-])(=O)=O)C=1Cl.[Na+].[Na+].[Na+]
[EPA Substance Registry System]

Benzoic acid, 5-[(3-carboxy-5-methyl-4-oxo- 2,5-cyclohexadien-1-ylidene)( 2,6-dichloro-3-sulfophenyl) methyl]-2-hydroxy-3-methyl-, trisodium salt(1667-99-8)
Hazard InformationBack Directory
[Chemical Properties]

dark brown powder
[Uses]

Chromeazurol S (cas# 1667-99-8) is a compound useful in organic synthesis.Dyes and metabolites.
[Preparation]

2,4-Dichloro-3-formylbenzenesulfonic acid?and 2-Hydroxy-3-methylbenzoic acid condensation, its product oxidation and changed into sodium salt.
[Properties and Applications]

red light blue. Soluble in water for brown light yellow, slightly soluble in ethanol for red light brown. In concentrated sulfuric acid for hot magenta, after dilution to orange, and then generate a orange precipitation. Dye aqueous solution and sodium hydroxide as 3H-indol-3-one,2-(1,3-dihydro-3-oxo-2H-indol-2-ylidene)-1,2-dihydro- blue.
Standard Ironing Fastness Light Fastness Fulling Persperation Fastness Soaping Water
Alkali Acid
ISO 4 3 4 2 4-5 4 5
[Purification Methods]

The crude phenolic triphenylmethanecarboxysulfonic acid triNa salt (40g) is dissolved in water (250mL) and filtered. Then conc HCl (50mL) is added to the filtrate, with stirring. The precipitate is filtered off, washed with HCl (2M) and dried. It is redissolved in water (250mL), and precipitation is repeated twice more in a water bath at 70o. It is dried under vacuum over solid KOH (first), then P2O5 [Martynov et al. Zh Analyt Khim 32 519 1977]. It has also been purified by paper chromatography using n-butanol, acetic acid and water (7:3:1). First and second spots were extracted. It chelates Al and Be. It is used also for estimating fluoride. [Beilstein 11 IV 707.]
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[TSCA ]

TSCA listed
[HS Code ]

29189900
[Storage Class]

11 - Combustible Solids
Spectrum DetailBack Directory
[Spectrum Detail]

Mordant Blue 29(1667-99-8)IR1
Mordant Blue 29(1667-99-8)IR2
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