| Identification | Back Directory | [Name]
3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate) | [CAS]
16697-49-7 | [Synonyms]
3,4,6-Tri-O-benzyl--D-mannopyranose 1,2-(Methyl Orthoacetate)
3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate)
1,2-O-(1-Methoxyethylidene)-3,4,6-tris-O-(phenylMethyl)-β-D-Mannopyranose
β-D-Mannopyranose, 1,2-O-(1-Methoxyethylidene)-3,4,6-tris-O-(phenylMethyl)-
3,4,6-Tri-O-benzyl-1,2-O-(1-methoxyethylidene)-beta-D-mannopyranose min. 98% | [Molecular Formula]
C30H34O7 | [MDL Number]
MFCD00270088 | [MOL File]
16697-49-7.mol | [Molecular Weight]
506.592 |
| Chemical Properties | Back Directory | [Appearance]
White Solid | [Melting point ]
74-76°C | [Boiling point ]
601.1±55.0 °C(Predicted) | [density ]
1.22±0.1 g/cm3(Predicted) | [storage temp. ]
Refrigerator | [solubility ]
Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly) | [form ]
Solid | [color ]
White to Off-White |
| Hazard Information | Back Directory | [Chemical Properties]
White Solid | [Description]
3,4,6-Tri-O-benzyl-β-D-mannopyranose 1,2-(methyl orthoacetate) is a synthetic intermediate used in glycosylation reactions. Typically, the methyl orthoester protecting group is first removed by mild acid hydrolysis, producing a glycosyl donor. Removal of the O-benzyl protecting groups is performed late in the synthesis. | [Uses]
3,4,6-Tri-O-benzyl-β-D-mannopyranose 1,2-(Methyl Orthoacetate) (cas# 16697-49-7) is a compound useful in organic synthesis. | [References]
[1] JOSé R. MARINO-ALBERNAS. Synthesis and Growth Inhibitory Properties of Glycosides of 1-O-Hexadecyl-2-O-methyl-sn-glycerol, Analogs of the Antitumor Ether Lipid ET-18-OCH3 (Edelfosine)[J]. Journal of Medicinal Chemistry, 1996, 39 17: 3241-3247. DOI: 10.1021/jm960164j
[2] NILANJANA CHAKRABORTY Marc d’Alarcao. An anionic inositol phosphate glycan pseudotetrasaccharide exhibits high insulin-mimetic activity in rat adipocytes[J]. Bioorganic & Medicinal Chemistry, 2005, 13 24: Pages 6732-6741. DOI: 10.1016/j.bmc.2005.07.020 |
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