| Identification | More | [Name]
Phenyl tribromomethyl sulfone | [CAS]
17025-47-7 | [Synonyms]
PHENYL TRIBROMETHYL SULPHONE
PHENYL TRIBROMOMETHYL SULFONE
PHENYLTRIBROMOMETHYLSULPHONE
SYNCURE BMPS
TBMPS
TRIBROMOMETHYL PHENYL SULFONE
TRIBROMOMETHYLPHENYLSULPHONE
(TRIBROMOMETHYL)SULFONYLBENZENE
[(tribromomethyl)sulfonyl]-benzen
[(tribromomethyl)sulphonyl]benzene
Phenyl Trieromomethyl Sulfone
Tribromomethyl
Benzene, (tribromomethyl)sulfonyl-
SYNCUREBMS4-BENZOYL-4''-METHYLDIPHENYLSULPHIDE
TRIBORMOMETHYL PHENYL SULFONE | [EINECS(EC#)]
241-096-6 | [Molecular Formula]
C7H5Br3O2S | [MDL Number]
MFCD00060068 | [Molecular Weight]
392.89 | [MOL File]
17025-47-7.mol |
| Chemical Properties | Back Directory | [Melting point ]
145-147 °C(lit.)
| [Boiling point ]
373.8±42.0 °C(Predicted) | [density ]
2.300±0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
soluble in Acetone | [form ]
powder to crystal | [color ]
White to Almost white | [InChI]
InChI=1S/C7H5Br3O2S/c8-7(9,10)13(11,12)6-4-2-1-3-5-6/h1-5H | [InChIKey]
DWWMSEANWMWMCB-UHFFFAOYSA-N | [SMILES]
C1(S(C(Br)(Br)Br)(=O)=O)=CC=CC=C1 | [CAS DataBase Reference]
17025-47-7(CAS DataBase Reference) | [EPA Substance Registry System]
17025-47-7(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [TSCA ]
TSCA listed | [HS Code ]
2930.90.2900 |
| Hazard Information | Back Directory | [Uses]
The derivatives of phenyl tribromomethyl sulfone as novel compounds with potential pesticidal activity
| [Synthesis]
General procedure: The NaOH solution (15% w/w, 8 mL) was cooled to 5 °C and Br2 (0.4 mL, 15 mmol, 3 eq.) was added dropwise while keeping the temperature of the mixture below 10 °C. The NaOH solution was cooled to 5 °C and Br2 (0.4 mL, 15 mmol, 3 eq.) was added to the mixture. Subsequently, phenylmethyl sulfone (5 mmol, 1 eq.) was added all at once. The reaction mixture was stirred at 75 °C for the indicated time (see Table 1). After completion of the reaction, the mixture was cooled to room temperature, the precipitate was collected by filtration, washed with H2O, dried in air and finally recrystallized by 2-PrOH. Detailed characterization data of the resulting tribromomethyl phenyl sulfone are given in the Supplementary Material. | [References]
[1] Journal of Organic Chemistry, 1986, vol. 51, # 17, p. 3369 - 3371
[2] Tetrahedron Letters, 2012, vol. 53, # 48, p. 6606 - 6610,5 |
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