ChemicalBook--->CAS DataBase List--->17249-80-8

17249-80-8

17249-80-8 Structure

17249-80-8 Structure
IdentificationMore
[Name]

3-CHLOROTHIOPHENE
[CAS]

17249-80-8
[Synonyms]

3-CHLOROTHIOPHENE
3-thienyl chloride
[EINECS(EC#)]

605-636-8
[Molecular Formula]

C4H3ClS
[MDL Number]

MFCD00043887
[Molecular Weight]

118.58
[MOL File]

17249-80-8.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to light yellow liquid
[Melting point ]

-62 °C
[Boiling point ]

137-139 °C(lit.)
[density ]

1.276 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.553(lit.)
[Fp ]

99 °F
[storage temp. ]

Flammables area
[form ]

Liquid
[color ]

Clear colorless to light yellow
[Specific Gravity]

1.276
[BRN ]

105255
[Exposure limits]

ACGIH: TWA 5 ppm (Skin)
OSHA: TWA 10 ppm(30 mg/m3)
NIOSH: IDLH 500 ppm; TWA 10 ppm(30 mg/m3)
[InChI]

InChI=1S/C4H3ClS/c5-4-1-2-6-3-4/h1-3H
[InChIKey]

QUBJDMPBDURTJT-UHFFFAOYSA-N
[SMILES]

C1SC=CC=1Cl
[CAS DataBase Reference]

17249-80-8(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

T,F,Xi
[Risk Statements ]

R61:May cause harm to the unborn child.
R10:Flammable.
R36:Irritating to the eyes.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36:Wear suitable protective clothing .
S7/9:Keep container tightly closed and in a well-ventilated place .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

-
[Hazard Note ]

Irritant
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29339900
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 3
Repr. 1B
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Tenoxicam-->3-Chlorothiophene-2-carboxylic acid-->2-Acetyl-3-chlorothiophene-->3-Chlorothiophene-2-carbonyl chloride-->3-Hexylthiophene-->2-Bromo-3-chlorothiophene-->2-Acetyl-4-chlorothiophene-->Methyl 3-thiophenecarboxylate 97
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to light yellow liquid
[Uses]

3-Chlorothiophene was used in the synthesis of poly(3-chlorothiophene) films by direct oxidation in mixed electrolytes of boron trifluoride diethyl etherate and trifluroacetic acid.
[Synthesis Reference(s)]

Journal of Heterocyclic Chemistry, 14, p. 281, 1977 DOI: 10.1002/jhet.5570140224
[General Description]

Electrochemical homopolymerization of 3-chlorothiophene and copolymerization with 3-methylthiophene in ionic liquid has been investigated by potentiodynamic and galvanostat methods.
Spectrum DetailBack Directory
[Spectrum Detail]

3-CHLOROTHIOPHENE(17249-80-8)MS
3-CHLOROTHIOPHENE(17249-80-8)1HNMR
3-CHLOROTHIOPHENE(17249-80-8)13CNMR
3-CHLOROTHIOPHENE(17249-80-8)IR1
3-CHLOROTHIOPHENE(17249-80-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Chlorothiophene, 98%(17249-80-8)
[Alfa Aesar]

3-Chlorothiophene, 98%(17249-80-8)
[Sigma Aldrich]

17249-80-8(sigmaaldrich)
[TCI AMERICA]

3-Chlorothiophene,>97.0%(GC)(17249-80-8)
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