| Identification | Back Directory | [Name]
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE | [CAS]
192139-92-7 | [Synonyms]
TsDPEN
(R,R)-N-
RuCl[(R,R)-Tsdpen](p-cymene)
RuCl(p-cymene)[(R,R)-Ts-DPEN]
((R,r)-2-amino-1,2-diphenylethy)[(4-tolyl)sulfonyl]amido](pcymene)ruthenium(II)chloride
[((R,R)-2-AMino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]aMido](chloro)(η6-p-cyMene)rutheniuM
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
((R,R)-2-aMino-1,2-diphenylethyl0[(4-tolyl)sulfonyl]aMino](p-cyMene)RutheniuM(II)chloride
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%
Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II), Min. 95% C31H35ClN2O2RuS
Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(R,R)-Tsdpen](p-cyMene)
Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(R,R)-Tsdpen](p-cyMene)
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene)
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-
cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene)
RutheniuM,[N-[(1R,2R)-2-(aMino-kN)-1,2-diphenylethyl]-4-MethylbenzenesulfonaMidato-kN]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-Methylethyl)benzene]-
[N-[(1R,2R)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-4-(1-methylethyl)benzene]-ruthenium | [Molecular Formula]
C21H21ClN2O2RuS.C10H14 | [MDL Number]
MFCD10567385 | [MOL File]
192139-92-7.mol | [Molecular Weight]
636.219 |
| Chemical Properties | Back Directory | [Melting point ]
215 °C | [storage temp. ]
2-8°C | [solubility ]
Deuterated Chloroform, DMF | [form ]
solid | [color ]
yellow to dark brown | [Optical Rotation]
[α]20/D 116°, c = 0.1 in chloroform | [Sensitive ]
air sensitive | [InChIKey]
AZFNGPAYDKGCRB-MNPNNRAMNA-M | [SMILES]
C1=C(S(=O)(=O)N([C@H](C2=CC=CC=C2)[C@H](N)C2=CC=CC=C2)[Ru]Cl)C=CC(C)=C1.C1=CC(C)=CC=C1C(C)C |&1:6,13,r| |
| Hazard Information | Back Directory | [Chemical Properties]
Orange to brown powder | [Uses]
Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:
- Quinolines
- N-Alkyl ketimines
- Antitumor and antiproliferative derivatives of natural products isolated from bacteria
- Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation
Catalyst with improved performance modified via microenvironment engineering of nanocages | [General Description]
RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium. | [Synthesis]
In a dry reactor, ruthenium chloride catalyst ( 167 mg , 0.273 mmol), mono-p-toluenesulfonic acid diamine ( 0.546 mmol), and triethylamine ( 155 μL , 1.11 mmol) were dissolved in dry isopropanol ( 5.5 m L ), and then the resulting reaction mixture was hea |
| Questions And Answer | Back Directory | [Reaction]
This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.
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