| Identification | More | [Name]
Tetrabutylammonium perchlorate | [CAS]
1923-70-2 | [Synonyms]
TETRABUTYLAMMONIUM PERCHLORATE
TETRA-N-BUTYLAMMONIUM PERCHLORATE
n,n,n-tributyl-1-butanaminiuperchlorate
TETRABUTYLAMMONIUM PERCHLORATE ELECTRO-C HEMICAL GRADE
Tetrabutylammonium perchlorate, contains max. 10% water, 99%
TETRABUTYLAMMONIUM PERCHLORATE REAGENT
Tetrabutylammoniumperchlorate,min.98%
1-Butanaminium, N,N,N-tributyl-, perchlorate
tetra-n-butylammonium perchlorate, electrochemical grade
Tetra-n-butylammonium perchlorate, 99+%
Tetrabutylazanium perchlorate
Tetrabutylammonium perchlorate, min. 98%
Tetrabutylammonium perchlorate, 99%, contains max. 10% water
Tetrabutylaminium·perchlorate
Hyperchloric acidanion·tetrabutylaminium
Tetrabutylaminium·hyperchloric acidanion | [EINECS(EC#)]
217-655-5 | [Molecular Formula]
C16H36ClNO4 | [MDL Number]
MFCD00038722 | [Molecular Weight]
341.91 | [MOL File]
1923-70-2.mol |
| Chemical Properties | Back Directory | [Appearance]
white powder | [Melting point ]
211-215 °C | [density ]
1.0387 (rough estimate) | [refractive index ]
1.6800 (estimate) | [storage temp. ]
2-8°C, sealed storage, away from moisture | [solubility ]
acetonitrile: 0.1 g/mL, clear, colorless
| [form ]
Crystalline Powder | [color ]
White | [Stability:]
Stable. Strong oxidizer-contact with combustible material may cause fire. Incompatible with strong reducing agents, combustible materials. Do not heat. | [Water Solubility ]
Soluble in acetonitrile and ethanol. Very slightly soluble in water. | [Sensitive ]
Hygroscopic | [BRN ]
3579274 | [InChI]
InChI=1S/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1 | [InChIKey]
KBLZDCFTQSIIOH-UHFFFAOYSA-M | [SMILES]
[N+](CCCC)(CCCC)(CCCC)CCCC.Cl([O-])(=O)(=O)=O | [CAS DataBase Reference]
1923-70-2(CAS DataBase Reference) | [EPA Substance Registry System]
1923-70-2(EPA Substance) |
| Questions And Answer | Back Directory | [Synthesis]
Synthesis of Tetrabutylammonium Perchlorate: A concentrated aqueous solution of tetrabutylammonium hydroxide is added to a saturated solution of NaClO4. The resulting mixture is stirred at room temperature for several hours. After the reaction is complete, the resulting white precipitate is filtered and washed. Finally, it is purified by recrystallization from an aqueous methanol solution.  |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS03,GHS07 | [Signal word ]
Danger | [Hazard statements ]
H272-H315-H319-H335 | [Precautionary statements ]
P210-P302+P352-P305+P351+P338 | [Hazard Codes ]
O,Xi | [Risk Statements ]
R5:Heating may cause an explosion.
R8:Contact with combustible material may cause fire.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S17:Keep away from combustible material .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN 1479 5.1/PG 2
| [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
5.1 | [PackingGroup ]
II | [HS Code ]
28299000 | [Storage Class]
5.1B - Oxidizing hazardous materials | [Hazard Classifications]
Eye Irrit. 2
Ox. Sol. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
white powder | [Uses]
Tetrabutylammonium perchlorate is a tetraalkylammonium salt that can be used in phase-transfer catalysis. | [Uses]
Suitable for use as a polarographic supporting electrolyteTetra-n-butylammonium perchlorate is used as a supporting electrolyte in polarographic measurements. | [Uses]
Tetrabutylammonium perchlorate is a polarographic supporting electrolyte. | [General Description]
| [reaction suitability]
reagent type: oxidant | [Purification Methods]
Crystallise the perchlorate from EtOH ethyl acetate, from n-hexane or diethyl ether/acetone mixture, ethyl acetate or hot CH2Cl2. Dry it in a vacuum at room temperature over P2O5 for 24hours. [Anson et al. J Am Chem Soc 106 4460 1984, Ohst & Kochi J Am Chem Soc 108 2877 1986, Collman et al. J Am Chem Soc 108 2916 1986, Blau & Espenson J Am Chem Soc 108 1962 1986, Gustowski et al. J Am Chem Soc 108 1986, Ikezawa & Kutal J Org Chem 52 3299 1987, Beilstein 4 IV 557.] |
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| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
China Langchem Inc.
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0086-21-58956006 |
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www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm |
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