| Identification | More | [Name]
Bis(triphenylphosphine)iminium chloride | [CAS]
21050-13-5 | [Synonyms]
BIS(TRIPHENYLPHOSPHINE)IMINIUM CHLORIDE BIS(TRIPHENYLPHOSPHINE)IMINIUMHLORIDE BIS(TRIPHENYLPHOSPHORANYLIDENE)AMMONIUM CHLORIDE HEXAPHENYLDIPHOSPHAZENIUM CHLORIDE PHOSPHORUS(1+), TRIPHENYL(P,P,P-TRIPHENYLPHOSPHINEIMIDATO-KN)-, CHLORIDE, (T-4)- PPNCI Bis(triphenylphosphine)iminium chloride~PPNCl triphenyl(P,P,P-triphenylphosphine imidato)phosphorus(1+) chloride Bis(Triphenylphosphoranylidene)AmmoniumChloride97% Bis(triphenylphosphine)iminiumchloride,97% ppncl bis(triphenylphosphoranylidene)ammonium Bis-(triphenylphosphino)-iminium chloride Bis(triphenylphosphine)iminium chloride, Hexaphenyldiphosphazenium chloride, PPNCl | [EINECS(EC#)]
244-170-6 | [Molecular Formula]
C36H34Cl2N2P2 | [MDL Number]
MFCD00151523 | [Molecular Weight]
627.52 | [MOL File]
21050-13-5.mol |
| Chemical Properties | Back Directory | [Melting point ]
270-272 °C(lit.)
| [storage temp. ]
2-8°C
| [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Powder | [color ]
white | [Water Solubility ]
Moderately soluble in water. | [BRN ]
4097979 | [InChI]
InChI=1S/C36H30ClNP2/c37-40(34-25-13-4-14-26-34,35-27-15-5-16-28-35,36-29-17-6-18-30-36)38-39(31-19-7-1-8-20-31,32-21-9-2-10-22-32)33-23-11-3-12-24-33/h1-30H | [InChIKey]
QMTYWEYUVVWPQL-UHFFFAOYSA-N | [SMILES]
P(Cl)(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)N=P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1 | [CAS DataBase Reference]
21050-13-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . R20:Harmful by inhalation. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . S38:In case of insufficient ventilation, wear suitable respiratory equipment . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S22:Do not breathe dust . | [WGK Germany ]
3
| [F ]
10 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Inhalation Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
Co-catalyst used with a chiral Cobalt-salen complex for the asymmetric addition of carbon dioxide to propylene oxide. Also used in the preparation of 5-Hydroxy-clethodim Sulfoxide. | [Uses]
suzuki reaction | [General Description]
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