ChemicalBook--->CAS DataBase List--->2113-57-7

2113-57-7

2113-57-7 Structure

2113-57-7 Structure
IdentificationMore
[Name]

3-Bromobiphenyl
[CAS]

2113-57-7
[Synonyms]

3-BROMOBIPHENYL
3-BROMODIPHENYL
BROMOBIPHENYL(3-)
PBB NO 2
1,1’-(biphenyl,3-bromo-
1,1’-biphenyl,3-bromo-(3-bromobiphenyl)
3-Bromo-1,1'-biphenyl
3-bromo-1’-biphenyl
3-bromo-bipheny
Biphenyl, 3-bromo-
m-Bromobiphenyl
3-BROMOBIPHNYL
pbb 2
3-BROMOBISPHENOLA
[1,1'-Biphenyl]-3-yl bromide
1-Bromo-3-phenylbenzene
3-Xenyl bromide
Biphenyl-3-yl bromide
[EINECS(EC#)]

218-304-9
[Molecular Formula]

C12H9Br
[MDL Number]

MFCD00000082
[Molecular Weight]

233.1
[MOL File]

2113-57-7.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to pale yellow liquid
[Melting point ]

93-94 °C
[Boiling point ]

300 °C
[bp ]

300 °C
[density ]

1.398 g/mL at 25 °C(lit.)
[refractive index ]

1.637-1.641
[Fp ]

110 °C
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

Powder
[color ]

Light yellow to gray-beige
[Water Solubility ]

Insoluble
[Merck ]

4188
[BRN ]

2043191
[InChIKey]

USYQKCQEVBFJRP-UHFFFAOYSA-N
[CAS DataBase Reference]

2113-57-7(CAS DataBase Reference)
[NIST Chemistry Reference]

1,1'-Biphenyl, 3-bromo-(2113-57-7)
[EPA Substance Registry System]

2113-57-7(EPA Substance)
Questions And AnswerBack Directory
[Description]

3-Bromobiphenyl is an important industrial raw material, but also a very widely used organic synthesis intermediates, it is widely used in pharmaceutical, liquid crystal industry and other fields. In recent years, the export volume of 3-Bromobiphenyl in our country is increasing day by day, the main export object is some liquid crystal display production enterprises in Japan and South Korea.
[synthesis]

Add 1-bromo-3-iodobenzene (4.67 g, 16.5mmol), phenylboronic acid (1.83 g, 15.0 mmol), Pd (OAc)2 (101 mg, 0.450 mmol), PPh3 (239 mg, 0.911 mmol), and K2CO3 (6.23 g, 45.1 mmol) to a 200 mL twonecked round-bottom flask. Add toluene (40 mL) and water (40 mL) via syringe and reflux the mixture (bath temp. 100°C) for 24 h. Extract the resulting mixture with ethyl acetate (30 mL x 3). Dry the combined organic layer over Na2SO4 and concentrate in vacuo. Purify the residue to silica gel column chromatography (eluent:hexane).
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[RTECS ]

DV1750000
[TSCA ]

Yes
[HS Code ]

29039990
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Biphenyl-3-boronic acid-->3-PHENYLBENZENESULFONYL CHLORIDE-->N-PHENYL-3-BIPHENYLAMINE-->3-PHENYLBENZYLAMINE
Hazard InformationBack Directory
[General Description]

Clear yellow viscous liquid. Insoluble in water.
[Reactivity Profile]

3-BROMOBIPHENYL(2113-57-7) may be sensitive to light. This compound may react with oxidizing materials.
[Air & Water Reactions]

Insoluble in water.
[Fire Hazard]

Flash point data for this chemical are not available. 3-BROMOBIPHENYL is probably combustible.
[Chemical Properties]

Colorless to pale yellow liquid
[Uses]

3-Bromobiphenyl is utilized as an electrochemical immunosensor based on poly(dopamine) coated gold nanocluster for brominated flame retardants.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 41, p. 24, 1976 DOI: 10.1021/jo00863a005
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

3-Bromobiphenyl(2113-57-7).msds
Spectrum DetailBack Directory
[Spectrum Detail]

3-Bromobiphenyl(2113-57-7)MS
3-Bromobiphenyl(2113-57-7)1HNMR
3-Bromobiphenyl(2113-57-7)13CNMR
3-Bromobiphenyl(2113-57-7)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Bromobiphenyl, 97%(2113-57-7)
[Alfa Aesar]

3-Bromobiphenyl, 99%(2113-57-7)
[Sigma Aldrich]

2113-57-7(sigmaaldrich)
[TCI AMERICA]

3-Bromobiphenyl,>98.0%(GC)(2113-57-7)
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