ChemicalBook--->CAS DataBase List--->2231-57-4

2231-57-4

2231-57-4 Structure

2231-57-4 Structure
IdentificationMore
[Name]

Thiocarbohydrazide
[CAS]

2231-57-4
[Synonyms]

AURORA 1561
CARBONOTHIOIC DIHYDRAZIDE
TCH
THIOCARBAZIDE
THIOCARBOHYDRAZIDE
THIOCARBONOHYDRAZIDE
THIOCARBONYLDIHYDRAZIDE
1,3-Diamino-2-Thiourea
Carbohydrazide, thio-
Hydrazinecarbohydrazonothioic acid
hydrazinecarbohydrazonothioicacid
thio-carbohydrazid
Thiocarbonic dihydrazide
thiocarbonicdihydrazide
USAF ek-7372
usafek-7372
THIOCARBOHYDRAZIDE, FOR ELECTRON MICROSC OPY
thiocarbazide1
Thiocarbazide: (Thiocarbohydrazide)
[EINECS(EC#)]

218-769-8
[Molecular Formula]

CH6N4S
[MDL Number]

MFCD00007616
[Molecular Weight]

106.15
[MOL File]

2231-57-4.mol
Chemical PropertiesBack Directory
[Appearance]

white to grey-beige crystalline powder
[Melting point ]

171-174 °C (dec.)(lit.)
[Boiling point ]

230.1±23.0 °C(Predicted)
[density ]

1.273 (estimate)
[refractive index ]

1.5605 (estimate)
[storage temp. ]

Poison room
[solubility ]

Very slightly soluble (0.5g/100g, 25°C). Insoluble in ether.
[form ]

Crystalline Powder
[pka]

10.58±0.70(Predicted)
[color ]

White to gray-beige
[Sensitive ]

Light Sensitive
[BRN ]

506657
[CAS DataBase Reference]

2231-57-4(CAS DataBase Reference)
[NIST Chemistry Reference]

Carbonothioic dihydrazide(2231-57-4)
[EPA Substance Registry System]

2231-57-4(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T+
[Risk Statements ]

R5:Heating may cause an explosion.
R26/28:Very Toxic by inhalation and if swallowed .
R36/38:Irritating to eyes and skin .
R21:Harmful in contact with skin.
[Safety Statements ]

S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S38:In case of insufficient ventilation, wear suitable respiratory equipment .
S36/37:Wear suitable protective clothing and gloves .
S1:Keep locked up .
[RIDADR ]

UN 2811 6.1/PG 1
[WGK Germany ]

3
[RTECS ]

FF2975000
[F ]

4.4-8
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

I
[HS Code ]

29309090
[Hazardous Substances Data]

2231-57-4(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrogen-->Hydrogen Sulfide-->Formylhydrazine
[Preparation Products]

Metribuzin-->Dithizone-->3-thio-4-amino-6-t-butyl-1,2,4-triazine-5-one-->4-Amino-6-(tert-butyl)-3-mercapto-1,2,4-triazin-5(4H)-one-->4-AMINO-5-(3-BROMOPHENYL)-4H-1,2,4-TRIAZOLE-3-THIOL-->4-AMINO-5-(2-THIENYL)-4H-1,2,4-TRIAZOLE-3-THIOL-->4-Amino-5-(2-chlorobenzyl)-4H-1,2,4-triazole-3-thiol-->3H-1,2,4-Triazole-3-thione,4-amino-2,4-dihydro-5-(1-methylethyl)-(9CI)-->ethyl 3-hydrazino-5-methyl-1H-pyrazole-4-carboxylate-->4-AMINO-5-(3-FLUOROPHENYL)-4H-1,2,4-TRIAZOLE-3-THIOL
Hazard InformationBack Directory
[General Description]

Crystalline needles and plates. Used in electron microscopy to produce electron-opaque deposits for ultra structural analysis.
[Reactivity Profile]

THIOCARBAZIDE is a thioamide, which may behave as a weak base and therefore will react with acids forming salts with production of heat. THIOCARBAZIDE may react with acids and reducing agents to form toxic hydrogen sulfide gas. This may be vigorous depending on the nature of the reducing agent. Organic amides/imides react with azo and diazo compounds to generate toxic gases. The combustion of these compounds generates mixed oxides of nitrogen (NOx).
[Health Hazard]

High oral toxicity.
[Fire Hazard]

When heated to decomposition THIOCARBAZIDE emits very toxic fumes of nitrogen oxides and sulfur oxides.
[Chemical Properties]

white to grey-beige crystalline powder
[Uses]

Thiocarbohydrazide is used in electron microscopy to produce electron-opaque deposits for ultra structural analysis. It is used in the synthesis of oxazine grass ketones.
[Definition]

ChEBI: Thiocarbohydrazide is a thiocarbonyl compound.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Carbonothioic dihydrazide(2231-57-4).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Thiocarbohydrazide(2231-57-4)MS
Thiocarbohydrazide(2231-57-4)IR1
Thiocarbohydrazide(2231-57-4)IR2
Thiocarbohydrazide(2231-57-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Thiocarbohydrazide, 98%(2231-57-4)
[Alfa Aesar]

Thiocarbohydrazide, 97%(2231-57-4)
[Sigma Aldrich]

2231-57-4(sigmaaldrich)
[TCI AMERICA]

Thiocarbohydrazide,>98.0%(T)(2231-57-4)
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