ChemicalBook--->CAS DataBase List--->22364-68-7

22364-68-7

22364-68-7 Structure

22364-68-7 Structure
IdentificationMore
[Name]

2-Methylbenzyl cyanide
[CAS]

22364-68-7
[Synonyms]

2-METHYLBENZYL CYANIDE
(2-METHYLPHENYL)ACETONITRILE
O-METHYLBENZYL CYANIDE
O-METHYLPHENYLACETONITRILE
O-TOLYLACETONITRILE
O-XYLYL CYANIDE
2-methyl-benzeneacetonitril
2-Methylbenzeneacetonitrile
2-Tolylacetonitrile
Acetonitrile, o-tolyl-
Benzeneacetonitrile, 2-methyl-
-Methylbenzylcyanide
-Methylphenylacetonitrile
o-tolyl-acetonitril
2-Methylbenzyl cyanide~2-Methylphenylacetonitrile
Tolylacetonitrile
o-Methyl Benzyl Cyanide 2-Methyl Benzyl Cyanide
o-Tolylacetonitrile, 98+%
2-METHYLPHENYLACETONITRILE/O-TOLYLACETONITRILE
2-TOLYLACETONITRILE 99%
[EINECS(EC#)]

244-937-5
[Molecular Formula]

C9H9N
[MDL Number]

MFCD00001904
[Molecular Weight]

131.17
[MOL File]

22364-68-7.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to orange-reddish liquid
[Melting point ]

142-143 °C
[Boiling point ]

244-250 °C
[density ]

1.056 g/mL at 25 °C(lit.)
[refractive index ]

1.5264-1.5284
[Fp ]

>110°C
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Specific Gravity]

1.056
[Water Solubility ]

Slightly soluble in water. Soluble in benzene, ethyl ether, ethanol.
[BRN ]

907182
[Exposure limits]

NIOSH: IDLH 25 mg/m3
[LogP]

1.910 (est)
[CAS DataBase Reference]

22364-68-7(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Methylbenzyl cyanide(22364-68-7)
Safety DataBack Directory
[Symbol(GHS) ]

Skull and Crossbones (GHS06)
GHS06
[Signal word ]

Danger
[Hazard statements ]

H302-H312-H315-H319-H331-H335
[Precautionary statements ]

P261-P280-P304+P340-P305+P351+P338-P405-P501a
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S36/37:Wear suitable protective clothing and gloves .
S37/39:Wear suitable gloves and eye/face protection .
S27:Take off immediately all contaminated clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

3439
[RTECS ]

AM2290000
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29269090
[Toxicity]

mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02089,
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Dimethyl sulfate-->Benzeneacetonitrile-->Propanedinitrile, 2-(2-methylphenyl)--->4-methyl-N-[(2-methylphenyl)methylideneamino]benzenesulfonamide-->Tributyl(cyanomethyl)tin-->(Trimethylsilyl)acetonitrile-->4-Isoxazoleboronic acid pinacol ester-->2-Methylbenzyl chloride-->Sodium cyanide-->2-Tolylboronic acid
[Preparation Products]

2-(2-Amino-4-biphenyl)propionitrile-->2-(4-aminophenyl)propiononitrile-->2-(4-(Acetylamino)-3-nitrophenyl)propionitrile-->2-(4-(Acetylamino)phenyl)propionitrile-->2-(4-Acetamino-3-chlorophenyl)propionitrile-->o-Toluamide-->2,2'-Dimethylbiphenyl
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Methylbenzyl cyanide(22364-68-7).msds
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to orange-reddish liquid
[Uses]

o-Tolylacetonitrile is used as an important raw material and intermediate in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. It is also used as an organic and chemical intermediate.
[Definition]

ChEBI: A nitrile that is acetonitrile where one of the methyl hydrogens is substituted by a 2-methylphenyl group.
[Synthesis Reference(s)]

Synthesis, p. 40, 1987 DOI: 10.1055/s-1987-27834
Spectrum DetailBack Directory
[Spectrum Detail]

2-Methylbenzyl cyanide(22364-68-7)MS
2-Methylbenzyl cyanide(22364-68-7)1HNMR
2-Methylbenzyl cyanide(22364-68-7)13CNMR
2-Methylbenzyl cyanide(22364-68-7)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Methylbenzyl cyanide, 98%(22364-68-7)
[Alfa Aesar]

o-Tolylacetonitrile, 98+%(22364-68-7)
[TCI AMERICA]

o-Xylyl Cyanide,>98.0%(GC)(22364-68-7)
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