ChemicalBook--->CAS DataBase List--->27774-13-6

27774-13-6

27774-13-6 Structure

27774-13-6 Structure
IdentificationMore
[Name]

Vanadyl sulfate
[CAS]

27774-13-6
[Synonyms]

VANADYL SULFATE, TRIHYDRATE
c.i.77940
ci77940
oxo(sulfato(2-)-o)-vanadiu
oxo(sulfato(2-)-O)-Vanadium
oxo[sulfato(2-)-o]-vanadiu
oxosulfato-vanadiu
oxysulfato-vanadiu
vanadiumoxidesulfate(vo(so4))
vanadyl
vanadylsulfate(vo(so4))
vanadylsulfate(vso5)
Oxysulfato vanadium (IV)
VANADIUM OXYSULFATE (VANADYL SULFATE)
vanadium oxide sulphate
VANADYL SULFATE, 97+%
VANADYL SULPHATE (VANADIUM IV SULPHATE)
Vandanyl
Vanadium, oxosulfato(2-)-.kappa.O-
VANADIUMOXYSULPHATE
[EINECS(EC#)]

248-652-7
[Molecular Formula]

O5SV
[MDL Number]

MFCD00149935
[Molecular Weight]

163
[MOL File]

27774-13-6.mol
Chemical PropertiesBack Directory
[Appearance]

Vanadyl sulfate is a pale blue crystalline powder. Odorless.
[Melting point ]

105°C
[density ]

2.06[at 20℃]
[solubility ]

soluble in H2O
[form ]

Solid
[color ]

Blue
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[Water Solubility ]

soluble
[LogP]

-1.031 (est)
[CAS DataBase Reference]

27774-13-6(CAS DataBase Reference)
[EPA Substance Registry System]

27774-13-6(EPA Substance)
Safety DataBack Directory
[Risk Statements ]

R22:Harmful if swallowed.
R36/38:Irritating to eyes and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

UN 2931/9152
[Safety Profile]

A poison and an inhalation hazard. Poison by intravenous, intraperitoneal, and subcutaneous routes. Mutation data reported. When heated to decomposition it emits toxic fumes of VOx and SOx. See also SULFATES and VANADIUM COMPOUNDS.
[Hazardous Substances Data]

27774-13-6(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sulfurous Acid-->Vanadium(V) oxide
Hazard InformationBack Directory
[General Description]

A blue crystalline solid. Very soluble in water. Denser than water. Contact may irritate skin, eyes, and mucous membranes. May be toxic by ingestion, inhalation and skin absorption.
[Reactivity Profile]

VANADYL SULFATE(27774-13-6) has weak oxidizing or reducing powers. Redox reactions can however still occur.
[Air & Water Reactions]

Very soluble in water.
[Health Hazard]

Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
[Potential Exposure]

Vanadyl sulfate is used as a fixative for textile dyes, a colorant for glass and ceramics; a reducing agent and a catalyst.
[Fire Hazard]

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.
[Shipping]

UN2931 Vanadyl sulfate, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
[Incompatibilities]

Vanadyl sulfate has weak oxidizing or reducing powers. Redox reactions can however still occur. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Vanadyl sulfate may attack metals; sulfates react with aluminum, magnesium.
[Chemical Properties]

Vanadyl sulfate is a pale blue crystalline powder. Odorless.
[Physical properties]

The dihydrate, VOSO4?2H2O is a blue black crystalline powder, soluble in water.
[Uses]

The dihydrate is a mordant in dyeing and printing fabrics; used in preparing aniline black; a colorant in ceramics to form blue and green glazes; used in making colored glass; and a reducing agent.
[Definition]

ChEBI: Vanadyl sulfate is a vanadium coordination entity and a metal sulfate.
[Preparation]

Vanadyl sulfate is prepared by passing sulfur dioxide through a cold solution of vanadium pentoxide in sulfuric acid, followed by crystallization:
V2O5 + H2SO4 + H2O + SO2 → 2VOSO4 + 2H2O
[Flammability and Explosibility]

Nonflammable
[Veterinary Drugs and Treatments]

Nonflammable
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Vanadium oxysulfate(27774-13-6).msds
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