| Identification | Back Directory | [Name]
1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE- | [CAS]
28075-50-5 | [Synonyms]
cyclohexenyl triflate
1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-
cyclohexen-1-yl trifluoromethanesulfonate
cyclohex-1-en-1-yl trifluoromethanesulfonate
1-Cyclohexenyl trifluoroMethanesulfonate 97%
Cyclohex-1-en-1-yl trifluoromethanesulphonate
CYCLOHEX-1-EN-1-YL TRIFLUOROMETHANESULPHONATE - NEW PRODUCT
Methanesulfonic acid, 1,1,1-trifluoro-, 1-cyclohexen-1-yl ester
Cyclohex-1-en-1-yl triflate, 1-{[(Trifluoromethyl)sulphonyl]oxy}cyclohex-1-ene | [Molecular Formula]
C7H9F3O3S | [MDL Number]
MFCD06411281 | [MOL File]
28075-50-5.mol | [Molecular Weight]
230.21 |
| Chemical Properties | Back Directory | [Boiling point ]
84-87 °C4 mm Hg(lit.)
| [density ]
1.315 g/mL at 25 °C(lit.)
| [Fp ]
160 °F
| [storage temp. ]
2-8°C | [form ]
Liquid | [color ]
Colorless to yellow | [InChI]
1S/C7H9F3O3S/c8-7(9,10)14(11,12)13-6-4-2-1-3-5-6/h4H,1-3,5H2 | [InChIKey]
WVSCRRLWRRANJY-UHFFFAOYSA-N | [SMILES]
FC(F)(F)S(=O)(=O)OC1=CCCCC1 |
| Hazard Information | Back Directory | [Uses]
Cyclohex-1-en-1-yl Trifluoromethanesulfonate is used a reactant in the regioselective preparation of phenylpyrrolidines via C-H functionalization of amines with aryl halides. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 51, p. 277, 1986 DOI: 10.1021/jo00352a039 | [General Description]
1-Cyclohexenyl trifluoromethanesulfonate, also known as 1-cyclohexenyl triflate, is a cyclohexenyl sulfonate. Its trifluoromethylation reaction in the presence of different monodentate biaryl phosphine ligands has been investigated. The asymmetric Heck reaction of 1-cyclohexenyl trifluoromethanesulfonate using palladium complexes of phosphine oxazoline ligand has been studied. |
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