| Identification | More | [Name]
ALUMINUM TRIFLUOROMETHANESULFONATE | [CAS]
74974-61-1 | [Synonyms]
ALUMINIUM TRIFLATE
ALUMINIUM TRIFLUOROMETHANESULFONATE
ALUMINIUM TRIFLUOROMETHANESULPHONATE
ALUMINUM TRIFLATE
ALUMINUM TRIFLUOROMETHANESULFONATE
Aluminumtrifluoromethanesulfonate,99%(Aluminumtriflate)
Aluminium triflate~Trifluoromethanesulphonic acid aluminium salt
ALUMINUM TRIFLUOROMETHANESULFONATE, 99.9 %
Aluminium trifluoromethanesulfonate,98%
Aluminumtrifluoromethanesulfonate,98%
trifluoromethanesulfonic acid aluminum salt
Aluminium trifluoromethanesulphonate 99%
Aluminiumtrifluoromethanesulphonate99%
ALUMINUM TRIFLUOROMETHANESULFONATE (ALUMINUM TRIFLATE) | [EINECS(EC#)]
218-362-5 | [Molecular Formula]
C3AlF9O9S3 | [MDL Number]
MFCD00143596 | [Molecular Weight]
474.19 | [MOL File]
74974-61-1.mol |
| Chemical Properties | Back Directory | [Appearance]
White powder | [Melting point ]
300 °C(lit.) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
soluble in ether, acetone, acetonitrile, and diglyme; poorly soluble in nitromethane; sparingly soluble in SO2 and SO2 ClF. | [form ]
Powder | [color ]
White | [Water Solubility ]
Insoluble in water. | [Hydrolytic Sensitivity]
6: forms irreversible hydrate | [Sensitive ]
Hygroscopic | [Stability:]
hygroscopic | [InChI]
InChI=1S/CHF3O3S.Al.3H/c2-1(3,4)8(5,6)7;;;;/h(H,5,6,7);;;; | [InChIKey]
GCRKPTQIRSZTMM-UHFFFAOYSA-N | [SMILES]
C(F)(F)(F)S(O)(=O)=O.[AlH3] | [CAS DataBase Reference]
74974-61-1(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
C,Xi | [Risk Statements ]
R34:Causes burns.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 3261 8/PG 3
| [WGK Germany ]
3
| [Hazard Note ]
Corrosive | [TSCA ]
No | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29049090 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
White powder | [Uses]
Aluminum trifluoromethanesulfonate is used in pharmaceutical intermediates. | [Uses]
Lewis acid used as a catalyst for Friedel–Crafts, ketalization, nucleophilic substitution, hydroalkoxylation, methoxycarbonyla- tion, rearrangement, and epoxide ring-opening reactions. | [Preparation]
Can be prepared from aluminum trichloride and tribromide by heating with triflic acid in anhydrous conditions. Preparations from triethylaluminum, aluminum carbide, and aluminum isopropoxide have also been described. | [Reactions]
Friedel-Crafts Reactions.
Aluminum trifluoromethanesulfonate has been used for the Friedel-Crafts alkylation reaction of toluene with isopropyl and tert-butyl chlorides (eq 1), and for theacylationofbenzeneandtoluenewithacetylandbenzoylchlo- rides in low to moderate yields. Intramolecular Friedel-Crafts acylation of an aromatic compound with Meldrum’s acid has also been reported using catalytic amounts of Al(OTf) 3 . Acylation of 2-methoxynaphthalene with acetic anhydride has been reported using Al(OTf) 3 and lithium perchlorate as an additive to afford the corresponding 6-acetylated adduct in 83% yield. Effective acylation of arenes with carboxylic acids has also been disclosed using polystyrene-supported Al(OTf)3.
| [reaction suitability]
core: aluminum
reagent type: catalyst |
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