| Identification | More | [Name]
TIN(II) TRIFLUOROMETHANESULFONATE | [CAS]
62086-04-8 | [Synonyms]
STANNOUS TRIFLUOROMETHANESULFONATE
TIN(II) TRIFLATE
TIN(II) TRIFLUOROMETHANESULFONATE
TIN(II) TRIFLUOROMETHANESULPHONATE
TIN TRIFLATE
TIN TRIFLUOROMETHANESULFONATE
TRIFLUOROMETHANESULFONIC ACID TIN(2) SALT
TRIFLUOROMETHANESULFONIC ACID TIN(II) SALT
Stannous triflate~Tin(II) triflate
Tin(II) trifluoromethanesulphonate, tech.
Zinc(II)trifluoromethanesulfonate
Tin(II)trifluoromethanesulfonate,99%(Tintriflate)
Stannous trifluoromethanesulfonate, Tin(II) triflate
Bis(trifluoromethanesulfonic acid) tin(II) salt
Bis(trifluoromethanesulfonic acid)tin(II) salt
Tin(II)bis(trifluoromethanesulfonate)
Trifluoromethanesulfonic acid tin(II) | [Molecular Formula]
C2F6O6S2Sn | [MDL Number]
MFCD00191251 | [Molecular Weight]
416.85 | [MOL File]
62086-04-8.mol |
| Chemical Properties | Back Directory | [Appearance]
White to yellowish powder | [Melting point ]
≥300 °C (lit.) | [storage temp. ]
Refrigerator | [form ]
Powder | [color ]
White to yellow | [Water Solubility ]
Insoluble in water. | [Sensitive ]
Moisture Sensitive | [Stability:]
hygroscopic | [InChI]
1S/2CHF3O3S.Sn/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2 | [InChIKey]
RBGLVWCAGPITBS-UHFFFAOYSA-L | [SMILES]
FC(F)(F)S(=O)(=O)O[SnH2]OS(=O)(=O)C(F)(F)F | [CAS DataBase Reference]
62086-04-8(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Description]
Mild Lewis acid, primarily used to generate tin(II) enolates for stereoselective aldol and Michael reactions; [2,3]-Wittig and Ireland-Claisen rearrangements; addition of tin(II) acetylides to aldehydes; asymmetric allylation of aldehydes. | [Chemical Properties]
White to yellowish powder | [Uses]
Tin(II) trifluoromethanesulfonate is a mild Lewis acid used for stereoselective aldol and Michael reactions; [2,3]-Wittig and Ireland-Claisen rearrangements, Horner-Wadsworth-Emmons reactions, asymmetric [3 + 2] cycloaddition, ring opening reactions and Friedel-Crafts reactions. | [reaction suitability]
core: tin
reagent type: catalyst | [storage]
Moisture and air sensitive; all handling and storage should be done under nitrogen. |
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