| Identification | More | [Name]
2-Bromo-5-nitrothiazole | [CAS]
3034-48-8 | [Synonyms]
2-BROMO-5-NITROTHIAZOLE
AKOS 90293
BROMO(2-)-5-NITRO THIAZOLE
BUTTPARK 43\57-57
2-Bromo-5-nitro-1,3-thiazole
5-Nitro-2-bromothiazole
Thiazole, 2-bromo-5-nitro-
2-Bromo-5-nitrothiazole ,98% | [EINECS(EC#)]
221-226-8 | [Molecular Formula]
C3HBrN2O2S | [MDL Number]
MFCD00005317 | [Molecular Weight]
209.02 | [MOL File]
3034-48-8.mol |
| Chemical Properties | Back Directory | [Appearance]
YELLOW TO BROWN CRYSTALLINE POWDER | [Melting point ]
85-88 °C (dec.) (lit.) | [Boiling point ]
289.7±13.0 °C(Predicted) | [density ]
2.1273 (estimate) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2–8 °C | [form ]
Crystalline Powder | [pka]
-2.84±0.10(Predicted) | [color ]
Yellow to brown | [Water Solubility ]
Slightly soluble in water. | [Detection Methods]
HPLC | [BRN ]
4856 | [InChI]
InChI=1S/C3HBrN2O2S/c4-3-5-1-2(9-3)6(7)8/h1H | [InChIKey]
ANIJFZVZXZQFDH-UHFFFAOYSA-N | [SMILES]
S1C([N+]([O-])=O)=CN=C1Br | [CAS DataBase Reference]
3034-48-8(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Bromo-5-nitrothiazole(3034-48-8) | [EPA Substance Registry System]
3034-48-8(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [RTECS ]
XJ2986000
| [TSCA ]
Yes | [HS Code ]
29339900 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
YELLOW TO BROWN CRYSTALLINE POWDER | [Uses]
2-Bromo-5-nitrothiazole is used as a building block. It is used as an intermediate to produce other chemicals. | [Application]
The reaction of 2-Bromo-5-nitrothiazole with weakly basic secondary aliphatic amines produces the expected 2-amino product from nucleophilic substitution of bromine. However, the reaction of isomeric 5-bromo-2-nitrothiazole with such amines produces the expected mixture of the 5-amino product and the 2-amino 5-nitrothiazole rearrangement product. |
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