| Identification | More | [Name]
Octadecyl methacrylate | [CAS]
32360-05-7 | [Synonyms]
METHACRYLIC ACID OCTADECYL ESTER
METHACRYLIC ACID STEARYL ESTER
N-OCTADECYL METHACRYLATE
OCTADECYL 2-METHYL-2-PROPENOATE
OCTADECYL METHACRYLATE
STEARYL METHACRYLATE
2-methyl-2-propenoicacioctadecylester
2-Propenoicacid,2-methyl-,octadecylester
octadecylmethacrylate(stearylmethacrylate)
STEARYL METHACRYLATE, TECH.
METHACRYLIC ACID STEARYL ESTER (STABILIZED WITH MEHQ) 95+%
Octadecylmethacrylat
N-STEARYL METHACRYLATE
Stearyl Methacrylate (stabilized with MEHQ)
2-Methylpropenoic acid octadecyl ester
Acriester S | [EINECS(EC#)]
251-013-5 | [Molecular Formula]
C22H42O2 | [MDL Number]
MFCD00026683 | [Molecular Weight]
338.57 | [MOL File]
32360-05-7.mol |
| Chemical Properties | Back Directory | [Melting point ]
18-20 °C(lit.)
| [Boiling point ]
195 °C6 mm Hg(lit.)
| [density ]
0.864 g/mL at 25 °C(lit.)
| [vapor pressure ]
0.06Pa at 20℃ | [refractive index ]
n20/D 1.451(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,2-8°C | [Water Solubility ]
Insoluble in water | [form ]
powder to lump to clear liquid | [color ]
White or Colorless to Almost white or Almost colorless | [InChI]
1S/C22H42O2/c1-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19-20-24-22(23)21(2)3/h2,4-20H2,1,3H3 | [InChIKey]
HMZGPNHSPWNGEP-UHFFFAOYSA-N | [SMILES]
CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C | [LogP]
9.62 at 20℃ | [Uses]
Monomer for plastics, molding powders, solvent
coatings, adhesives, oil additives; emulsions
for textile, leather, paper finishing. | [CAS DataBase Reference]
32360-05-7(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Propenoic acid, 2-methyl-, octadecyl ester(32360-05-7) | [EPA Substance Registry System]
32360-05-7(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
1
| [TSCA ]
TSCA listed | [REACH Registrations]
Active | [HS Code ]
29161290 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Description]
Stearyl Methacrylate is an ester of Methacrylic Acid used as a raw material component in synthesizing polymers. It is a low-viscosity functional monomer with the characteristic high reactivity of acrylates and a long hydrophobic chain. Stearyl Methacrylate is a mixture of mainly C16 alcohol (Cetyl) and C18 alcohol (Stearyl) methacrylates. This compound forms homopolymers and copolymers prepared with acrylic acid and its salts, amides, esters, methacrylates, acrylonitrile, etc. | [Chemical Properties]
Octadecyl 2-methyl-2-acrylate, also known as octadecyl methacrylate, is a water-insoluble, white, waxy solid with a musty odor. Its molecular formula is C????H????O??, molecular weight is 338.57, melting point is 18-20 °C (lit.), boiling point is 195 °C, density is 0.864 g/mL at 25 °C (lit.), vapor pressure is 0.06 Pa at 20°C, and refractive index n??O/D is 1.451 (lit.). | [Synthesis]
1) 20.0 g of stearyl bromide (octadecyl bromide) was added to a 1000 mL single-necked flask with 250 mL of methylene chloride and 17.7 g of triethylamine, and 16.65 g of methacryloyl chloride was slowly added dropwise under stirring conditions. After the dropwise addition, the reaction was continued with stirring for 5 hours. Upon completion of the reaction, the reaction mixture was washed sequentially with water, saturated sodium carbonate solution and saturated sodium chloride solution. The organic phase was separated, dried with anhydrous sodium sulfate, concentrated under reduced pressure, and finally purified by column chromatography to afford 18.4 g of octadecyl 2-methyl-2-propenoate in 76% yield. | [References]
[1] Patent: CN105906664, 2016, A. Location in patent: Paragraph 0041; 0042 |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|