ChemicalBook--->CAS DataBase List--->3481-02-5

3481-02-5

3481-02-5 Structure

3481-02-5 Structure
IdentificationMore
[Name]

Cyclopropyl phenyl ketone
[CAS]

3481-02-5
[Synonyms]

BENZOYLCYCLOPROPANE
CYCLOPROPYL PHENYL KETONE
CYCLOPROPYL-PHENYL-METHANONE
Ketone, cyclopropyl phenyl
Methanone, cyclopropylphenyl-
Methanone,cyclopropylphenyl-
Phenyl cyclopropyl ketone
Cyclopropylphenylketone,97%
[EINECS(EC#)]

222-458-2
[Molecular Formula]

C10H10O
[MDL Number]

MFCD00001294
[Molecular Weight]

146.19
[MOL File]

3481-02-5.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID
[Melting point ]

7-9 °C(lit.)
[Boiling point ]

121-123 °C15 mm Hg(lit.)
[density ]

1.058 g/mL at 25 °C(lit.)
[vapor density ]

5 (vs air)
[refractive index ]

n20/D 1.553(lit.)
[Fp ]

195 °F
[storage temp. ]

0-6°C
[form ]

clear liquid
[color ]

Colorless to Light yellow
[Water Solubility ]

Insoluble in water.
[BRN ]

1860145
[CAS DataBase Reference]

3481-02-5(CAS DataBase Reference)
[NIST Chemistry Reference]

Cyclopropyl phenyl ketone(3481-02-5)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H227
[Precautionary statements ]

P210e-P280a-P370+P378a-P501a-P210-P280-P370+P378-P403+P235-P501
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[HS Code ]

2914390090
Hazard InformationBack Directory
[Chemical Properties]

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID
[Uses]

Cyclopropyl phenyl ketone was used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It was used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
[Uses]

Cyclopropyl phenyl ketone is used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It is also used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 45, p. 2921, 1980 DOI: 10.1021/jo01302a038
Tetrahedron Letters, 16, p. 4389, 1975 DOI: 10.1016/S0040-4039(00)91132-8
Spectrum DetailBack Directory
[Spectrum Detail]

Cyclopropyl phenyl ketone(3481-02-5)MS
Cyclopropyl phenyl ketone(3481-02-5)1HNMR
Cyclopropyl phenyl ketone(3481-02-5)13CNMR
Cyclopropyl phenyl ketone(3481-02-5)IR1
Cyclopropyl phenyl ketone(3481-02-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Cyclopropyl phenyl ketone, 97%(3481-02-5)
[Sigma Aldrich]

3481-02-5(sigmaaldrich)
[TCI AMERICA]

Cyclopropyl Phenyl Ketone,>98.0%(GC)(3481-02-5)
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