| Identification | More | [Name]
3-Methyl-2-butanone | [CAS]
563-80-4 | [Synonyms]
1，1-Dimethyl acetone
3-METHYL-2-BUTANONE
3-Methylbutanone
ISOPROPYL METHYL KETONE
METHYL ISOPROPYL KETONE
MIPK
2-Acetylpropane
2-Butanone,3-methyl-
2-Methylbutan-3-one
3-Methylbutan-2-on
3-methyl-butan-2-one
3-Methylbutan-2-one
Isobutyl-1-methylketone
iso-C3H7COCH3
iso-Propylmethyldetone
Ketone, isopropyl methyl
Methyl butanone-2
Methylbutanone
methylisopropylcetone
Methylisopropylketon | [EINECS(EC#)]
209-264-3 | [Molecular Formula]
C5H10O | [MDL Number]
MFCD00008919 | [Molecular Weight]
86.13 | [MOL File]
563-80-4.mol |
| Chemical Properties | Back Directory | [Appearance]
MIPK is a colorless liquid with an acetonelike odor. | [Melting point ]
-92 °C (lit.) | [Boiling point ]
94-95 °C (lit.) | [density ]
0.805 g/mL at 25 °C(lit.)
| [vapor pressure ]
53.33 hPa (19.9 °C) | [refractive index ]
n20/D 1.388(lit.)
| [Fp ]
6 °C
| [storage temp. ]
Flammables area | [solubility ]
water: soluble8.21g/L at 20°C | [form ]
Liquid | [color ]
Clear colorless | [Odor]
at 0.10?%?in?dipropylene glycol. camphor | [explosive limit]
1.5-9%(V) | [Odor Threshold]
0.5ppm | [Water Solubility ]
6 g/L (20 ºC) | [Specific Heat Capacity]
Cp(liquid):179.9J/(g·K),at 25℃ | [Merck ]
14,6090 | [BRN ]
1071238 | [Henry's Law Constant]
1.1×10-1 mol/(m3Pa) at 25℃, Brockbank (2013) | [Dielectric constant]
16.57 | [Exposure limits]
TLV-TWA 700 mg/m3 (200 ppm); STEL
875 mg/m3 (250 ppm) (ACGIH). | [Cosmetics Ingredients Functions]
PERFUMING | [InChI]
1S/C5H10O/c1-4(2)5(3)6/h4H,1-3H3 | [InChIKey]
SYBYTAAJFKOIEJ-UHFFFAOYSA-N | [SMILES]
CC(C)C(C)=O | [LogP]
2.29 at 20℃ | [CAS DataBase Reference]
563-80-4(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Butanone, 3-methyl-(563-80-4) | [EPA Substance Registry System]
563-80-4(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS02 | [Signal word ]
Danger | [Hazard statements ]
H225 | [Precautionary statements ]
P210-P233-P240-P241-P242-P243 | [Hazard Codes ]
F | [Risk Statements ]
R11:Highly Flammable. | [Safety Statements ]
S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S33:Take precautionary measures against static discharges . | [OEB]
A | [OEL]
TWA: 200 ppm (705 mg/m3) | [RIDADR ]
UN 2397 3/PG 2
| [WGK Germany ]
1
| [RTECS ]
EL9100000
| [Autoignition Temperature]
475 °C | [Hazard Note ]
Highly Flammable | [TSCA ]
Yes | [REACH Registrations]
Active | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29141990 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Flam. Liq. 2 | [Safety Profile]
Poison by ingestion.
Mildly toxic by inhalation and skin contact.
Mutation data reported. A skin and eye
irritant. Flammable when exposed to heat or
flame; can react vigorously with oxidizing
materials. When heated to decomposition it
emits acrid smoke and irritating fumes. | [Hazardous Substances Data]
563-80-4(Hazardous Substances Data) | [Toxicity]
LD50 orally in male mice: 29.86 mmol/kg (Tanii) |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Oxygen-->Isobutyraldehyde-->2-Methyl-2-butanol-->2,3-dibromo-2-methylbutane-->DL-Mevalonolactone-->Dehydromevalonolactone-->Isoprene | [Preparation Products]
Imazaquin acid-->1,3,3-TRIMETHYLINDOLINOBENZOPYRYLOSPIRAN-->2,6-DIMETHYL-3,5-HEPTANEDIONE-->1,2,5-OXADIAZOLE-3-CARBOXYLIC ACID-->3-METHYL-1,2,5-OXADIAZOLE-->(1,2-DIMETHYL-PROPYL)-HYDRAZINE-->Imazamox-->Bromoform-->2-Amino-2,3-dimethylbutyronitrile-->2-Butanone, 3-methyl-, oxime-->Ethyl isobutyrylacetate-->N-AMYL ISOPROPYL KETONE-->2,3-DIMETHYLDECANE-->2,3,3-Trimethyl-5-methoxy-3H-indole |
| Hazard Information | Back Directory | [General Description]
A colorless liquid with a pleasant odor. Flash point below 70°F. Less dense than water. May be toxic by inhalation and skin absorption. Used as a solvent. | [Reactivity Profile]
Ketones, such as 3-METHYLBUTAN-2-ONE(563-80-4), are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4. | [Air & Water Reactions]
Highly flammable. Soluble in water. | [Hazard]
Toxic material. Embryo/fetal damage andneonatal toxicity. | [Health Hazard]
Irritating to the eyes, nose, throat, upper respiratory tract, and skin. | [Potential Exposure]
This ketone is used as a solvent for
nitrocellulose lacquers. | [Fire Hazard]
Special Hazards of Combustion Products: Acrid smoke and fumes | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce
vomiting. Do not make an unconscious person vomit | [Shipping]
UN23973-Methylbutan-2-one, Hazard Class: 3;
Labels: 3-Flammable liquid. | [Incompatibilities]
Vapors may form explosive mixture with
air. Ketones are incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides, nitrated amines, azo,
diazo, azido compounds, carbamates, organic cyanates | [Description]
MIPK is a colorless liquid with an acetonelike odor. Molecular weight = 86.15; Specific gravity(H2O:1) 5 0.81; Boiling point = 93℃. Freezingpoint 5 2 92℃; Vapor pressure 5 42 mmHg at 20℃; Flashpoint 5 6℃; Autoignition temperature 5 475℃. Explosivelimits: LEL 5 1.2%; UEL 5 8%. Hazard Identification(based on NFPA-704 M Rating System): Health 1,Flammability 4, Reactivity 0. Slightly soluble in water;solubility 5 0.5% at 20℃. | [Chemical Properties]
CLEAR COLOURLESS LIQUID | [Chemical Properties]
MIPK is a colorless liquid with an acetonelike odor. | [Waste Disposal]
Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All
federal, state, and local environmental regulations must
be observed. | [Uses]
Methyl isopropyl ketone (MIPK) is used asa solvent for lacquers. | [Uses]
Solvent for nitrocellulose lacquers. | [Definition]
ChEBI: 3-Methylbutan-2-one is a ketone. | [Preparation]
3-Methyl-2-butanone is produced by oxidation of Methyl-iso-propylcarbinol (2-Methyl-3-butanol).
| [Flammability and Explosibility]
Highlyflammable | [storage]
Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Prior to working with this chemical you should be trainedon its proper handling and storage. Before entering confinedspace where this chemical may be present, check to makesure that an explosive concentration does not exist. Store intightly closed containers in a cool, well-ventilated areaaway from aldehydes. Sources of ignition, such as smokingand open flames, are prohibited where methyl isopropylketone is used, handled, or stored in a manner that couldcreate a potential fire or explosion hazard. Use only nonsparking tools and equipment, especially when opening andclosing containers of methyl isopropyl ketone. Wherevermethyl isopropyl ketone is used, handled, manufactured, orstored, use explosion-proof electrical equipment andfittings. | [Purification Methods]
Reflux the ketone with a little KMnO4. Fractionate it through a spinning-band column, dry with CaSO4 and distil it. [Beilstein 1 IV 3287.] |
|
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|