ChemicalBook--->CAS DataBase List--->352-70-5

352-70-5

352-70-5 Structure

352-70-5 Structure
IdentificationMore
[Name]

3-Fluorotoluene
[CAS]

352-70-5
[Synonyms]

1-FLUORO-3-METHYLBENZENE
3-FLUOROTOLUENE
M-FLUOROTOLUENE
1-fluoro-3-methyl-benzen
1-Methyl-3-fluorobenzene
3-fluoromethylbenzene
benzene,1-fluoro-3-methyl-
meta-Fluorotoluene
m-Fluoromethylbenzene
Toluene, m-fluoro-
toluene,3-fluoro-
Toluene,m-fluoro-
4,4-Diiso-Octanyl Diphenylamine
Fluorotoluene2
m-Fluro Toluene
3-Fluorotoluene m-Fluorotoluene
3-Fluorotoluene,98%
3-Fluorotoluene 99%
3-Fluorotoluene99%
4,4''-DIISO-OCTANYLDIPHENYLAMINE(3-FLUOROTOLUENE)
[EINECS(EC#)]

206-524-8
[Molecular Formula]

C7H7F
[MDL Number]

MFCD00000339
[Molecular Weight]

110.13
[MOL File]

352-70-5.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to light yellow liquid
[Melting point ]

-87 °C
[Boiling point ]

115 °C(lit.)
[density ]

0.991 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.469(lit.)
[Fp ]

49 °F
[storage temp. ]

Store below +30°C.
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Specific Gravity]

0.991
[Water Solubility ]

immiscible
[Merck ]

14,4180
[BRN ]

1903631
[Dielectric constant]

5.4199999999999999
[InChI]

1S/C7H7F/c1-6-3-2-4-7(8)5-6/h2-5H,1H3
[InChIKey]

BTQZKHUEUDPRST-UHFFFAOYSA-N
[SMILES]

Cc1cccc(F)c1
[LogP]

2.75
[CAS DataBase Reference]

352-70-5(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzene, 1-fluoro-3-methyl-(352-70-5)
[EPA Substance Registry System]

352-70-5(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)
GHS02
[Signal word ]

Danger
[Hazard statements ]

H225
[Precautionary statements ]

P210-P370+P378-P403+P235
[Hazard Codes ]

F,Xi
[Risk Statements ]

R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 2388 3/PG 2
[WGK Germany ]

2
[RTECS ]

XT2578000
[Hazard Note ]

Flammable/Irritant
[TSCA ]

T
[REACH Registrations]

Inactive
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29036990
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Flam. Liq. 2
Raw materials And Preparation ProductsBack Directory
[Raw materials]

m-Toluidine-->3-Nitrotoluene-->3-Chloro-4-(3-fluorobenzyloxy)aniline-->3-Chloro-4-(3-fluorobenzyloxy)nitrobenzene
[Preparation Products]

3-Fluorobenzoyl chloride-->4-Fluoro-2-methylbenzoic acid-->3-Fluorophenylacetonitrile-->2-Fluoro-4-methylaniline-->4-Fluoro-2-methylaniline-->2-Fluorotoluene-->5-Fluoro-2-nitrobenzoic acid-->3-Fluorobenzotrichloride-->4-Fluoro-2-methyl-5-nitrobenzoic acid-->3-Fluorophenylacetone-->3-Fluoro-4-iodobenzoic acid-->3-Fluorobenzyl alcohol-->3-Fluoro-2-nitrotoluene
Hazard InformationBack Directory
[General Description]

A colorless liquid with an aromatic odor. Boiling point 239°C. Flash point 63°F. Density 0.991 g/cm3---may float or sink in water.
[Reactivity Profile]

3-FLUOROTOLUENE(352-70-5) may be incompatible with strong oxidizing and reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Generates toxic fluoride fumes when burned.
[Air & Water Reactions]

Highly flammable.
[Health Hazard]

Inhalation causes upper respiratory irritation. Irritating to skin and eyes. May be absorbed through the skin. Prolonged exposure may result in systemic toxic effects. Harmful if swallowed.
[Chemical Properties]

clear colorless to light yellow liquid
[Uses]

3-Fluorotoluene was used in gas phase selective synthesis of 3-fluorobenzaldehyde. It was used in generation of tolyl cations by chemical ionization in mass spectrometry.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 72, p. 4809, 1950 DOI: 10.1021/ja01166a506
[Purification Methods]

Purify it as for o-fluorotoluene. [Beilstein 5 H 290, 5 III 676, 5 IV 799.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-Fluoro-3-methylbenzene(352-70-5).msds
Spectrum DetailBack Directory
[Spectrum Detail]

3-Fluorotoluene(352-70-5)MS
3-Fluorotoluene(352-70-5)1HNMR
3-Fluorotoluene(352-70-5)13CNMR
3-Fluorotoluene(352-70-5)IR1
3-Fluorotoluene(352-70-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

3-Fluorotoluene, 98%(352-70-5)
[Sigma Aldrich]

352-70-5(sigmaaldrich)
[TCI AMERICA]

3-Fluorotoluene,>99.0%(GC)(352-70-5)
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