ChemicalBook--->CAS DataBase List--->3724-43-4

3724-43-4

3724-43-4 Structure

3724-43-4 Structure
IdentificationMore
[Name]

(Chloromethylene)dimethyliminium chloride
[CAS]

3724-43-4
[Synonyms]

(CHLOROMETHYLENE)DIMETHYLAMMONIUM CHLORIDE
CHLOROMETHYLENEDIMETHYLIMINIUM CHLORIDE
N-CHLOROMETHYLEN-N,N-DIMETHYLAMMONIUM CHLORIDE
VILSMEIER REAGENT
(Chloromethylene)dimethylammoniumchlorlde
n-(chloromethylene)-n-methyl-methanaminiuchloride
Vilsmeier
N-Chloromethylene-N,N-Dimethyl Ammonium Chloride
Methanaminium, N-(chloromethylene)-N-methyl-, chloride
(chlormethylene)dimethylammonium chloride
arnold's reagent
n,n-dimethylchloroformimidinium chloride
VILSMEIER SALT
(Chlormethylene)dimethylammonium chloride, Vilsmeier reagent
Chloro(dimethylamino)methylium chloride
Chlorodimethylformiminium chloride
Dimethyl(chloromethylene)ammonium chloride
Dimethylchloroformiminium chloride
N,N-Dimethylchloroformiminium chloride
(Chloromethylene)dimethylammonium chloride96%
[EINECS(EC#)]

425-970-6
[Molecular Formula]

C3H7Cl3N2
[MDL Number]

MFCD00011868
[Molecular Weight]

177.46
[MOL File]

3724-43-4.mol
Chemical PropertiesBack Directory
[Appearance]

Pale brown to yellowish-brown crystalline powder
[Melting point ]

132 °C (dec.) (lit.)
[Boiling point ]

204.27°C (rough estimate)
[density ]

1.3578 (rough estimate)
[refractive index ]

1.4525 (estimate)
[storage temp. ]

2-8°C
[form ]

Crystalline Powder
[color ]

Pale brown to yellow-brown
[Water Solubility ]

reacts
[Sensitive ]

Moisture Sensitive
[BRN ]

3566322
[InChI]

InChI=1S/C3H7ClN.ClH/c1-5(2)3-4;/h3H,1-2H3;1H/q+1;/p-1
[InChIKey]

QQVDYSUDFZZPSU-UHFFFAOYSA-M
[SMILES]

[N+](/C)(\C)=C\Cl.[Cl-]
[CAS DataBase Reference]

3724-43-4(CAS DataBase Reference)
[EPA Substance Registry System]

3724-43-4(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS05,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H302-H314-H360D
[Precautionary statements ]

P260-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
[Hazard Codes ]

T
[Risk Statements ]

R61:May cause harm to the unborn child.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R34:Causes burns.
R22:Harmful if swallowed.
R14:Reacts violently with water.
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3261
[WGK Germany ]

1
[F ]

8-10
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29252000
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Dam. 1
Repr. 1B
Skin Corr. 1A
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Thionyl chloride
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

(Chloromethylene)dimethyliminium chloride(3724-43-4).msds
Hazard InformationBack Directory
[Chemical Properties]

Pale brown to yellowish-brown crystalline powder
[Uses]

(Chloromethylene)dimethylammonium chloride is used in the synthesis of beta-lactams, n-vinyl substituted indoles and fused 2-pyridone rings and 2-azetidinones. It is used as a formylating agent and used in the preparation of anti-poxvirus agents. It is used in Staudinger reaction and Hundsdiecker-barton iododecarboxylation reaction. It is widely used for studying organic photosensitizers, which finds application in dye-sensitized solar cells.
[reaction suitability]

reaction type: C-C Bond Formation
Spectrum DetailBack Directory
[Spectrum Detail]

(Chloromethylene)dimethyliminium chloride(3724-43-4)Raman
(Chloromethylene)dimethyliminium chloride(3724-43-4)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(Chloromethylene)dimethylammonium chloride, 96%(3724-43-4)
[Alfa Aesar]

(Chloromethylene)dimethylammonium chloride, 96%(3724-43-4)
[Sigma Aldrich]

3724-43-4(sigmaaldrich)
[TCI AMERICA]

(Chloromethylene)dimethyliminium Chloride,>95.0%(T)(3724-43-4)
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