| Identification | More | [Name]
2,6-Pyridinedicarboxylic acid chloride | [CAS]
3739-94-4 | [Synonyms]
2,6-PYRIDINEDICARBONYL DICHLORIDE
2,6-PYRIDINEDICARBOXYLIC ACID CHLORIDE
PYRIDINE-2,6-DICARBONYL CHLORIDE
PYRIDINE-2,6-DICARBOXYLIC ACID CHLORIDE
2,6-Pyridinedicarbonyl chloride
pyridine-2,6-dicarbonyl dichloride
2,6-Pyridinedicarboxylicacid dichloride
2,6-PYRIDINEDICARBOXYLIC ACID CHLORIDE 97%
(S)-(-)-1-(4-METHOXYPHENYL)ETHANOL
2,6-Pyridinedicarbonyl chloride, Pyridine-2,6-dicarboxylic acid chloride
2,6-Bis(chlorocarbonyl)pyridine
2,6-Pyridinedicarbonyl dichloride ,97%
2,6-Pyridinebis(carbonyl chloride)
2,6-Pyridinebis(carboxylic acid chloride)
Pyridine-2,6-biscarbonyl chloride | [EINECS(EC#)]
223-125-4 | [Molecular Formula]
C7H3Cl2NO2 | [MDL Number]
MFCD00006289 | [Molecular Weight]
204.01 | [MOL File]
3739-94-4.mol |
| Chemical Properties | Back Directory | [Appearance]
white to brown crystalline powder, crystals or | [Melting point ]
56-58 °C (lit.) | [Boiling point ]
284 °C (lit.) | [density ]
1.4521 (rough estimate) | [refractive index ]
1.6100 (estimate) | [Fp ]
284°C | [storage temp. ]
Storage temp. 2-8°C | [form ]
Crystalline Powder, Crystals or Chunks | [pka]
-2.12±0.10(Predicted) | [color ]
White to brown | [Water Solubility ]
Insoluble in water. | [Sensitive ]
Moisture Sensitive | [Detection Methods]
HPLC,NMR | [BRN ]
131556 | [InChI]
InChI=1S/C7H3Cl2NO2/c8-6(11)4-2-1-3-5(10-4)7(9)12/h1-3H | [InChIKey]
GWHOGODUVLQCEB-UHFFFAOYSA-N | [SMILES]
C1(C(Cl)=O)=NC(C(Cl)=O)=CC=C1 | [CAS DataBase Reference]
3739-94-4(CAS DataBase Reference) | [NIST Chemistry Reference]
2,6-Pyridinedicarbony chloride(3739-94-4) | [Storage Precautions]
Store under nitrogen;Moisture sensitive |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302+H332-H317-H412 | [Precautionary statements ]
P261-P273-P280-P301+P312-P302+P352-P304+P340+P312 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S24/25:Avoid contact with skin and eyes . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
10-19-21 | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29333990 |
| Hazard Information | Back Directory | [Chemical Properties]
white to brown crystalline powder, crystals or | [Uses]
2,6-Pyridinedicarbonyl dichloride can be used as a starting material to synthesize:
- Pyridine-based polyamido-polyester optically active macrocycles by reacting with chiral diamine dihydrobromides.
- Pyridine-bridged 2,6-bis-carboxamide Schiff′s bases by treating with L-alanine or 2-methyl-alanine methyl esters.
- N,N′-bis(1-pyrenylmethyl)pyridine-2,6-dicarboxamide by reacting with 1-pyrenemethylamine hydrochloride in the presence of a base.
| [Uses]
2,6-Pyridinedicarboxylic acid chloride was used as the reagent during the synthesis of pyridine-based polyamido-polyester optically active macrocycles. It was used as starting reagent during the synthesis of pyridine-bridged 2,6-bis-carboxamide Schiff′s bases. It was used in the synthesis of N,N′-bis(1-pyrenylmethyl)pyridine-2,6-dicarboxamide.
| [Synthesis]
Pyridine-2,6-dicarboxylic acid (105 mg, 0.52 mmol) mixed with 7mL of thionyl
chloride was heated to reflux for 3 hours. After the excess thionyl chloride was
removed, a white solid was obtained and used for the following synthesis without
further purifications.
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