ChemicalBook--->CAS DataBase List--->3886-70-2

3886-70-2

3886-70-2 Structure

3886-70-2 Structure
IdentificationMore
[Name]

(R)-(+)-1-(1-Naphthyl)ethylamine
[CAS]

3886-70-2
[Synonyms]

(1R)-(1-NAPHTHALEN-1-YL)ETHANAMINE
D-A-(1-NAPHTHYL)ETHYLAMINE
(R)-(+)-1-(1-NAPHTHYL)ETHYLAMINE
(R)-1-(1-NAPHTHYL)ETHYLAMINE
(R) 1-(1-NAPTHYL)ETHYLAMINE
(R)-1-(NAPHTHALEN-1-YL)ETHANAMINE
(R)-(+)-1-(NAPHTHYL)ETHYLAMINE
(R)-(+)-A-(1-NAPHTHYL)ETHYLAMINE
(R)-(+)-ALPHA-(1-AMINOETHYL)NAPHTHALENE
(R)-(+)-ALPHA-(1-NAPHTHYL)ETHYLAMINE
(theta)-1-naphthalenemethanamin
(R)-(+)-α-Methyl-1-naphthalenemethylamine
R-PLUS-A-1-NAPHTHYL-ETHYLAMINE
(R)-(+)-1-(1-NAPHTHYL)ETHYLAMINE 99%
(R)-(+)-1-(Napthyl)ethylamine, 99%
(R)-(+)-alpha-(1-Naphthyl)ethylamine, 99+%
1-Naphthalenemethanamine, .alpha.-methyl-, (.alpha.R)-
(R)-(+)-1-(Naphth-1-yl)ethylamine
R-(+)-NAPHTHYLETHYLAMINE
(R)-(+)--(1-NAPHTHYL) ETHYLAMINE 98%
[EINECS(EC#)]

223-425-5
[Molecular Formula]

C12H13N
[MDL Number]

MFCD00064114
[Molecular Weight]

171.24
[MOL File]

3886-70-2.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liqui
[Melting point ]

135-136 °C
[alpha ]

60 º (c=2, CH3OH)
[Boiling point ]

153 °C11 mm Hg(lit.)
[density ]

1.067 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.623(lit.)
[Fp ]

>230 °F
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Slightly), Ethanol (Slightly), Methanol (Slightly)
[form ]

Liquid
[pka]

9.26±0.40(Predicted)
[color ]

brown
[Specific Gravity]

1.07
[Stability:]

Stable. Air-sensitive. Incompatible with acids, oxidizing agents, acid anhydrides, chloroformates, acid chlorides.
[optical activity]

[α]20/D +55°, c = 2 in ethanol
[Water Solubility ]

Soluble in water (<10/l).
[Sensitive ]

Air Sensitive
[BRN ]

2208025
[InChIKey]

RTCUCQWIICFPOD-SECBINFHSA-N
[CAS DataBase Reference]

3886-70-2(CAS DataBase Reference)
[EPA Substance Registry System]

3886-70-2(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

2735
[WGK Germany ]

3
[RTECS ]

QJ6963000
[F ]

10-34
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29214500
Raw materials And Preparation ProductsBack Directory
[Raw materials]

1-Naphthaldehyde-->D-Phenylglycinol
[Preparation Products]

1R,3R-chrysanthemic acid-->Cinacalcet hydrochloride-->N-((R)-1-(naphthalen-1-yl)ethyl)-3-(3-(trifluoroMethyl)phenyl)propanaMide-->1-ETHYLNAPHTHALENE-->(+/-)1-(1-Naphthyl)ethylamine-->Cinacalcet Impurity 9-->(R)-(-)-1-(1-NAPHTHYL)ETHYL ISOTHIOCYANATE-->(R)-(+)-N,N-DIMETHYL-1-(1-NAPHTHYL)ETHYLAMINE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

R-(+)-alpha-(1-Naphthyl)ethylamine(3886-70-2).msds
Hazard InformationBack Directory
[Chemical Properties]

Colorless to light yellow liqui
[Uses]

(R)-(+)-1-(1-Naphthyl)ethylamine(3886-70-2) is used in chiral synthesis in organic reactions including the synthesis of β-amino acids and the enantioselective of ketones to nitroolefins.
[Application]

Absolute configuration of primary amines determined using chiral (2-nitrophenyl)proline amides and 1H NMR.
[General Description]

(R)-(+)-1-(1-Naphthyl)ethylamine(3886-70-2) is a chiral derivatization reagent useful for all gas chromatography (GC) applications in the chiral field. It is specially selected to meet the requirements for derivatization reagents for enantiomeric excess determinations.
[Purification Methods]

Purify the amine by distillation in a good vacuum. [Mori et al. Tetrahedron 37 1343 1981, cf Wilson in Topics Stereochem (Allinger and Eliel eds) v o l 6 135 1971, Fredga et al. Acta Chem Scand 11 1609 1957.] The hydrochlorides crystallise from H2O [] D 18 ±3.9o (c 3, H2O), and the sulfates recrystallise from H2O as tetrahydrates m 230-232o. The RS-amine has b 153o/11mm, 156o/15mm, 183.5o/41mm [Blicke & Maxwell J Am Chem Soc 6 1 1780 1939]. [Beilstein 12 III 3111.]
Spectrum DetailBack Directory
[Spectrum Detail]

(R)-(+)-1-(1-Naphthyl)ethylamine(3886-70-2)1HNMR
(R)-(+)-1-(1-Naphthyl)ethylamine(3886-70-2)IR1
(R)-(+)-1-(1-Naphthyl)ethylamine(3886-70-2)IR2
(R)-(+)-1-(1-Naphthyl)ethylamine(3886-70-2)IR3
(R)-(+)-1-(1-Naphthyl)ethylamine(3886-70-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(R)-(+)-alpha-(1-Naphthyl)ethylamine, 99+%(3886-70-2)
[Alfa Aesar]

(R)-(+)-1-(1-Naphthyl)ethylamine, ChiPros 99+%, ee 98+%(3886-70-2)
[Sigma Aldrich]

3886-70-2(sigmaaldrich)
[TCI AMERICA]

(R)-(+)-1-(1-Naphthyl)ethylamine,>99.0%(GC)(3886-70-2)
3886-70-2 suppliers list
Company Name: Yangzhou Qinyuan Pharmatech Co.,ltd
Tel: +86-18752526868 , +86-18752526868
Website: http://www.yzqyyykj.com/en/
Company Name: Hebei Mojin Biotechnology Co., Ltd
Tel: +86-13288715578 +86-13231137666 , +86-13231137666
Website: www.mojinchemical.com
Company Name: Hebei Yanxi Chemical Co., Ltd.
Tel: +8617531190177 , +8617531190177
Website: www.chemicalbook.com/manufacturer/hebei-yanxi-chemical-283/
Company Name: Changzhou Rokechem Technology Co., Ltd.
Tel: 18758118018 , 18758118018
Website: www.rokechem.com
Company Name: Capot Chemical Co.,Ltd.
Tel: 571-85586718 +8613336195806 , +8613336195806
Website: http://www.capotchem.com
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: +86-0371-55170693 +86-19937530512 , +86-19937530512
Website: https://www.tianfuchem.com/
Company Name: Chembon Pharmaceutical Co., Ltd.
Tel: +86-28-8425-2981
Website: www.chembon.com.cn
Company Name: ATK CHEMICAL COMPANY LIMITED
Tel: +undefined-21-51877795
Website: www.atkchemical.com
Company Name: Zjartschem
Tel: +86-571-8723 8903 jocelynpan@zjarts.com
Website: www.zjartschem.com/eacpzs.asp?dlb_id=12
Company Name: career henan chemical co
Tel: +86-0371-86658258
Website: https://www.coreychem.com/
Company Name: NINGBO INNO PHARMCHEM CO., LTD.
Tel: 13867897135
Website: en.nbinno.com
Company Name: Shanghai Arbor Chemical Co., Ltd.
Tel: 021-60451682
Website: www.chemicalbook.com/ShowSupplierProductsList31105/0.htm
Company Name: Jinan Finer Chemical Co., Ltd
Tel: +86-531-88989536 +86-15508631887 , +86-15508631887
Website: http://www.finerchem.com/
Company Name: Accela ChemBio Inc.
Tel: (+1)-858-699-3322
Website: www.accelachem.com
Company Name: Hebei Guanlang Biotechnology Co., Ltd.
Tel: +86-19930503282 , +86-19930503282
Website: https://www.chemicalbook.com/manufacturer/crovell/
Company Name: Cangzhou Wanyou New Material Technology Co.,Ltd
Tel: 18631714998
Website: www.chemicalbook.com/ShowSupplierProductsList1382651/0.htm
Company Name: Standardpharm Co. Ltd.
Tel: 86-714-3992388
Website: www.standardpharm.com
Company Name: Changzhou Carman Chemical Co., Ltd.
Tel: 15061933924
Website: www.chemicalbook.com/ShowSupplierProductsList1090088/0.htm
Tags:3886-70-2 Related Product Information
1217809-88-5 23364-44-5 20439-47-8 109-89-7 56-53-1 2624-44-4 554-68-7 86-88-4 75-04-7 2627-86-3 121-44-8 1229225-42-6 802918-36-1 1229224-93-4 694495-47-1 1428185-71-0 104774-87-0 1271930-12-1