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23364-44-5

23364-44-5 Structure

23364-44-5 Structure
IdentificationMore
[Name]

(1S,2R)-2-Amino-1,2-diphenylethanol
[CAS]

23364-44-5
[Synonyms]

(1R,2S)-(-)-2-AMINO-1,2-DIPHENYLETHANOL
(1R,2S)-2-AMINO-1,2-DIPHENYLETHANOL
(1R,2S)-(-)-DIPHENYL-2-AMINOETHANOL
(1R,2S)-(-)-ERYTHRO-2-AMINO 1,2-DIPHENYLETHANOL
(1S,2R)-(-)-2-AMINO-1,2-DIPHENYLETHANOL
(1S,2R)-(+)-2-AMINO-1,2-DIPHENYLETHANOL
(1S,2R)-2-AMINO-1,2-DIPHENYLETHANOL
(1S,2R)-(+)-DIPHENYL-2-AMINOETHANOL
BENZENEETHANOL, B-AMINO-A-PHENYL-, (AR,BS)-
BENZENEETHANOL, B-AMINO-A-PHENYL-, (AS,BR)-
(1S,2r)-(+)-2-Amino-1,2-Diphenylehanol
(1S,2R)-(+)-2-Amino-1,2-dipenylethanol
(1S,2R)-(+)-1,2-DIPHENYLHYDROXYETHYLAMINE
(1S,2R)-(+)-2-AMINO-1,2-DIPHENYLETHANOL 99% E.E. 98% ASSAY
(1S,2R)-(-)-1,2-DIPHENYLHYDROXYETHYLENEDIAMINE
(1S,2R)-(+)-2-Amino-1,2-diphenylethanol ,98% [ee:99%]
(1R,2S)-1,2-Diphenyl-1-amino-2-hydroxyethane
[EINECS(EC#)]

628-513-0
[Molecular Formula]

C14H15NO
[MDL Number]

MFCD00074960
[Molecular Weight]

213.27
[MOL File]

23364-44-5.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

142-144 °C(lit.)
[alpha ]

7 º (c=0.6, EtOH)
[Boiling point ]

374.3±37.0 °C(Predicted)
[density ]

1.148±0.06 g/cm3(Predicted)
[refractive index ]

7 ° (C=0.6, EtOH)
[storage temp. ]

2-8°C
[solubility ]

very faint turbidity in Methanol
[form ]

Crystalline Powder
[pka]

11.70±0.45(Predicted)
[color ]

White to beige
[optical activity]

[α]25/D +7.0°, c = 0.6 in ethanol
[Detection Methods]

HPLC,NMR
[BRN ]

1212828
[InChIKey]

GEJJWYZZKKKSEV-KGLIPLIRSA-N
[CAS DataBase Reference]

23364-44-5(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[F ]

9
[HS Code ]

29221990
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol can be used:
  • To prepare vanadium(V) Schiff base complexes, which are used as catalysts in the oxidation of sulfides and olefins.
  • To prepare chiral selectors, which are immobilized on aminated silica gel, applicable as chiral stationary phase in HPLC.
  • To immobilize on the frame of α-zirconium phosphate to yield layered zirconium phosphonates, which are used in the heterogeneous catalysis.
  • As a chiral auxiliary in the preparation of homopropargylic alcohols from aliphatic and aromatic aldehydes.

Questions And AnswerBack Directory
[Reaction]

  1. Ligand used to make chiral oxaborolidines for the enantioselective alkynylation of aldehydes
  2. Ligand used in organoindium reagents for asymmetric Barbier-type allylations
  3. Ligand used in organoindium reagents for asymmetric Barbier-type propargylations
Reactions of 23364-44-5
Spectrum DetailBack Directory
[Spectrum Detail]

(1S,2R)-2-Amino-1,2-diphenylethanol(23364-44-5)MS
(1S,2R)-2-Amino-1,2-diphenylethanol(23364-44-5)1HNMR
(1S,2R)-2-Amino-1,2-diphenylethanol(23364-44-5)13CNMR
(1S,2R)-2-Amino-1,2-diphenylethanol(23364-44-5)IR1
(1S,2R)-2-Amino-1,2-diphenylethanol(23364-44-5)IR2
(1S,2R)-2-Amino-1,2-diphenylethanol(23364-44-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(1S,2R)-2-Amino-1,2-diphenylethanol, 99%(23364-44-5)
[Alfa Aesar]

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol, 99%(23364-44-5)
[Sigma Aldrich]

23364-44-5(sigmaaldrich)
[TCI AMERICA]

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol,>99.0%(GC)(T)(23364-44-5)
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