ChemicalBook--->CAS DataBase List--->39148-24-8

39148-24-8

39148-24-8 Structure

39148-24-8 Structure
IdentificationBack Directory
[Name]

Chipco aliette WDG
[CAS]

39148-24-8
[Synonyms]

mikal
rhodax
ALIETTE
EFOSITE
32545rp
exp1659
hy-cote
hy-tona
ls74783
ls74-783
MIKAL(R)
r6triplo
Efosite-Al
FOSETYL AL
ALIETTE(R)
FOSETHYL-AL
PHOSTHYL-AL
fosetyl alu.
phosethyl-al
alietteextra
Fosetyl-alumin
FOSETYL AL 95%
efositealuminum
FOSETYL-ALUMINUM
FOSETYL-ALUMINIUM
aluminumphosethyl
phosethylaluminum
ALUMINIUM-FOSETYL
Fosetyl Aluminiun
FOSETIL-ALUMINIUM
aluminiumphosethyl
chipco aliette wdg
Epal(Rhone-Poulenc)
PHOSETHYL-ALUMINIUN
Aluminiumtriethylphosphonate
aluminumtris(ethylphosphite)
FOSETYL-ALUMINUM, 100MG, NEAT
aluminiumtris(ethylphosphonate)
aluminium tris(ethyl phosphite)
Aluminum tris(ethoxyphosphinate)
Aluminum tris(ethyl phosphonate)
aluminium triethyl triphosphonate
ALUMINIUMTRIS(O-ETHYLPHOSPHONATE)
ALUMINUM TRIS(O-ETHYL PHOSPHONATE)
FOSETYL-ALUMINIUM PESTANAL (ALUMINI-UMT&
phosphonicacidmonoethylesteraluminumsalt
Tris(phosphonic acid ethyl) aluminum salt
Phosphonicacid,monoethylester,aluminiumsalt
phosphonicacid,monoethylester,aluminumsalt(3:1)
[EINECS(EC#)]

254-320-2
[Molecular Formula]

C6H18AlO9P3
[MDL Number]

MFCD00144376
[MOL File]

39148-24-8.mol
[Molecular Weight]

354.1
Chemical PropertiesBack Directory
[Appearance]

White, crystalline solid or powder. Odorless.
[Melting point ]

>300°
[vapor pressure ]

< 10-7 Pa (25 °C)
[storage temp. ]

0-6°C
[form ]

solid
[pka]

4.7
[Water Solubility ]

110 g l-1 (20 °C)
[EPA Substance Registry System]

Phosphonic acid, monoethyl ester, aluminum salt(39148-24-8)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

41
[Safety Statements ]

26-39
[RIDADR ]

UN2783 (solid); UN3018 (liquid
[RTECS ]

SZ9640000
[Hazardous Substances Data]

39148-24-8(Hazardous Substances Data)
[Toxicity]

LD50 in rats, mice, Japanese quail, rabbits (mg/kg): 5800, 3700, 4997, 2680 orally; LD50 i.p. in rats: 550 mg/kg (Williams)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Ammonium hydroxide-->Ammonia-->Phosphorus trichloride-->Aluminum sulfate-->Diethyl phosphite-->COBALT(III) OXIDE BLACK
[Preparation Products]

ETHYLPHOSPHONIC ACID-->O-CRESOL-D8
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Chipco aliette WDG(39148-24-8).msds
Hazard InformationBack Directory
[Potential Exposure]

Organophosphate fungicide used on fruits, vegetables and nut crops; also on ornamentals and greenhouse products.
[First aid]

Speed in removing material from eyes and skin is of extreme importance. Eyes: Eye contact can cause dan gerous amounts of these chemicals to be quickly absorbed through the mucous membrane into the bloodstream. Immediately and gently flush eyes with plenty of warm or cold water (NO hot water) for at least 15 minutes, occa sionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Dermal contact can cause dangerous amounts of these chemicals to be absorbed into the bloodstream. Wearing the appropriate PPE equip ment and respirator for organophosphate pesticides, imme diately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Shampoo hair promptly if contaminated. Ingestion: Call poison control. Loosen all clothing. Never give any thing by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious, alert, and able to swallow, rinse mouth and have victim drink 4 to 8 oz of water do NOT induce vomiting but immediately administer slurry of activated charcoal (2 oz in 8 oz of water). If vic tim is UNCONSCIOUnited States OR HAVING CONVULSIONS, do nothing except keep victim warm. In some cases you may be specifically instructed by poison control to induce vomiting by way of 2 tablespoons of syrup of ipecac (adult) washed down with a cup of water. Do NOT give activated charcoal before or with ipecac syrup. Inhalation: Get medical aid. Do not contaminate yourself. Wearing the appropriate PPE equipment and respirator for organophosphate pesticides, immediately remove the victim from the contaminated area to fresh air. If the victim is not breathing, administer artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If breathing is difficult, administer oxygen through bag/mask apparatus until medi cal help arrives. Do not leave victim unattended.
[Shipping]

UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
[Incompatibilities]

In the presence of strong reducing agents such as hydrides, organophosphates form highly toxic and flammable phosphine gas. Contact with oxidizers can cause the release of toxic oxides of phosphorus. Decomposes in temperatures above 260℃.
[Chemical Properties]

White, crystalline solid or powder. Odorless.
[Waste Disposal]

Destruction by alkali hydroly sis or incineration. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by con tacting your regional EPA office.
[Uses]

Agricultural fungicide.
[Uses]

Fosetyl-aluminium (fosetyl-Al) is a systemic fungicide effective in controlling various Phycomycete diseases, in particular the downy mildews, Phyfophfhora and Pythium spp. It has also shown useful activity against several bacterial plant pathogens (e.g. Erwinia amylovara). It is widely used on a variety of crops including vines, fruit (bananas, citrus, pineapples, avocados, stone fruit and pome fruit), berries, vegetables, hops, ornamentals and turf.
[Uses]

Fungicide
[Agricultural Uses]

Fosetyl aluminum can be used as Fungicide: used on fruits, vegetables and nut crops; also on ornamentals and greenhouse products.
[Trade name]

32545 R®; ALIETTE®; ALIETTE® 80 WG; CHIPCO® ALIETTE WDG; EFOSITE-AL®; EFOSITE ALUMINUM®; EPAL®; LS-74783®; MIKAL®
[Environmental Fate]

Plant. Felsot and Pedersen (1991) reported that fosetyl-aluminum degrades in plants forming phosphonic acid which ionizes to the dianion phosphonate, HPO3–2.
[Metabolic pathway]

Fosetyl-Al undergoes rapid and extensive degradation and metabolism in soil, plants and animals. Cleavage of the P-O-ethyl linkage yielded phosphorous acid, ethanol and naturally incorporated components as the terminal products (Scheme 1).
[Degradation]

Aqueous solutions of fosetyl-Al undergo rapid degradation in strong acidic and alkaline conditions (1) with observed DT50 values of 5 days (pH 3) to 13 days (pH 13) but exhibit higher stability at pH values closer to neutrality (Bertrand et al., 1981). However, the results of biodegradability studies suggest that fosetyl-Al is readily biodegradable in environmental water (Mead, 1996).
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