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23564-05-8

23564-05-8 Structure

23564-05-8 Structure
IdentificationBack Directory
[Name]

Thiophanate-methyl
[CAS]

23564-05-8
[Synonyms]

DO
ROKO
nf44
ditek
f6385
SIGMA
COVER
3336G
trevin
easout
td1771
pei190
pelt14
pelt-44
fungo50
metoben
enovitm
CYCOSIN
AIMTHYL
TOPSIN M
Topxin-M
frumidor
fungitox
caligran
sipcasan
sipcavit
neotopsin
cercobinm
bas32500f
Midothane
MILDOTHANE
CEKUFANATO
Cercobin-M
sipcaplant
topsinnf-44
enovitsuper
LABILITE(R)
FUNGITOX(R)
TOPSIN M(R)
CERCOBINM-70
methyltopsin
enovitmethyl
thiophanatem
CERCOBIN-M(R)
topsinwpmethyl
cercobinmethyl
tiofanatemetile
methylthiofanate
methylthiophanate
THIOPHANAT-METHYL
THIOPHANATE-METHYL
O,O-Dimethyl analog
THIOPHANATE,METHYLESTER
Thiophanate methyl W.P.
topsinturfandornamentals
Thiophanate-methyl Standard
THIOPHANATE-METHYL, 1GM, NEAT
THIOPHANATE-METHYL PESTANAL, 250 MG
Thiophanate-methyl 1g [23564-05-8]
thiophanate-methyl (bsi,iso,ansi,jmaf)
1,2-BIS(METHOXYCARBONYLTHIOUEIDO) BENZENE
1,2-bis(methoxycarbonylthioureido)benzene
o-bis(3-methoxycarbonyl-2-thioureido)benzene
1,2-di-(3-Methoxy-carbonyl-2-thioureido)benzene
1,2-BIS(3-METHOXYCARBANYL-2-THIOUREIDO) BENZENE
1,2-Bis(3-(methoxycarbonyl)-2-thioureido)benzene
DIMETHYL-4,4'-O-PHENYLENEBIS-(3-THIOALLOPHANATE)
4,4’-o-phenylenebis(3-thio-allophanicacidimethylester
4,4'-o-Phenylenebis[3-thioallophanic Acid DiMethyl Ester
DIMETHYL((1,2-PHENYLENE)BIS(IMINOCARBONOTHIOYL))BISCARBA.
DIMETHYL([1,2-PHENYLENE]BIS(IMINOCARBONOTHIOYL))BIS(CARBAMATE)
1,2-DI(3-METHOXYCARBONYL-2-THIOUREIDO)BENZENE /THIOPHANATE METHYL
Thiophanate-methyl ,1,2-di-(3-methoxycarbonyl-2-thioureido)benzene
(1,2-phenylenebis(iminocarbonothioyl))bis-carbamicacidimethylester
[1,2-phenylenebis(iminocarbonothioyl)]bis-carbamicacidimethylester
[1,2-Phenylenebis(iminocarbonothioyl)]bis[carbamicacid]dimethylester
Carbamicacid,[1,2-phenylenebis(iminocarbonothioyl)]bis-,dimethylester
thiophanate-methyl (ISO) 1,2-di-(3-methoxycarbonyl-2-thioureido)benzene
Methyl N-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate
N,N'-[1,2-Phenylenebis(iMinocarbonothioyl)]biscarbaMic Acid C,C'-DiMethyl Ester
[EINECS(EC#)]

245-740-7
[Molecular Formula]

C12H14N4O4S2
[MDL Number]

MFCD00055294
[MOL File]

23564-05-8.mol
[Molecular Weight]

342.39
Chemical PropertiesBack Directory
[Appearance]

colourless crystals, or white or light brown powder
[Appearance]

Methyl thiophanate is a colorless crystals, prisms or light brown powder.
[Melting point ]

172°C
[storage temp. ]

0-6°C
[Stability:]

Stable. Incompatible with strong oxidizing agents, alkalies, copper salts.
[Water Solubility ]

<0.1 g/100 mL at 20 ºC
[Merck ]

13,9427
[EPA Substance Registry System]

Carbamic acid, [1,2-phenylenebis(iminocarbonothioyl)] bis-, dimethyl ester(23564-05-8)
Hazard InformationBack Directory
[Chemical Properties]

colourless crystals, or white or light brown powder
[Uses]

Thiophanate-Methyl is a systematic fungicide of the thiophanate class. Thiophanate-Methyl is commonly used in agriculture to protect against powdery mildew, rot and other fungal diseases in fruits, ve getables and other crops.
[Uses]

Systemic fungicide.
[Definition]

ChEBI: A member of the class of thioureas that is the dimethyl ester of (1,2-phenylenedicarbamothioyl)biscarbamic acid. A fungicide effective against a broad spectrum of diseases in fruit, vegetables, turf and other crops including eyespot, scab, powdery mildew a d grey mould.
[General Description]

Colorless crystals or light brown powder.
[Air & Water Reactions]

Insoluble in water.
[Reactivity Profile]

Thiophanate-methyl is incompatible with strong acids and bases, and with strong reducing agents such as hydrides. Produces flammable gaseous hydrogen with active metals or nitrides. Incompatible with strong oxidizing acids, peroxides. Incompatible with alkaline material. Forms complexes with copper salts .
[Fire Hazard]

Flash point data for Thiophanate-methyl are not available. Thiophanate-methyl is probably combustible.
[Potential Exposure]

Methyl thiophanate is thiocarbamate ester, used in the synthesis of polymers and in agriculture as pesticides, soil fumigants, and seed disinfectants.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Shampoo hair. Speed in removing material from skin is of extreme importance. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN2771 Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
[Incompatibilities]

Thiocarbamate esters are combustible; dust may form explosive mixture with air. Decomposes163℃Thiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of thiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithio carbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of thiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates are incompatible with acids, peroxides, and acid halides.
[Waste Disposal]

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.
Safety DataBack Directory
[Hazard Codes ]

Xn;N,N,Xn
[Risk Statements ]

20-43-50/53-68
[Safety Statements ]

36/37-46-60-61
[RIDADR ]

UN 3077
[RTECS ]

BA3675000
[HS Code ]

29309090
[Hazardous Substances Data]

23564-05-8(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Methanol-->o-Phenylenediamine-->PHOSGENE-->Sodium thiocyanate-->Methyl chloroformate-->ISOTHIOCYANATE, POLYMER-BOUND, 200-400-->METHYL THIOCYANOFORMATE
[Preparation Products]

Thiram+Thiophanate-methyl W.P.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Thiophanate-methyl (23564-05-8).msds
Questions And AnswerBack Directory
[Description]

Thiophanate methyl is a member of benzimidazole and a systemic fungicide with protective and curative activity against a broad spectrum of fungal diseases including leaf spots, blotches, blights, fruit spots, rots, sooty mould, scabs, bulb/corn/tuber decays, blossom blights, powdery mildews, certain rusts, and common soil borne crown and root rots. It is used on a variety of tree, vine, root crops, canola, and wheat, as well as on lawns and ornamentals. Thiophanate methyl is absorbed by the roots and leaves. Thiophanate-methyl has a low mammalian toxicity. But, it is an irritant and a skin sensitizer. It may also be mutagen. Moderate toxicity of thiophanate methyl is observed for aquatic organisms and earthworms. In EU, thiophanate methyl is approved to control fungal diseases on crops, while in Australia it is not registered for use on food-producing species, while it is only for the control of soil-borne diseases of ornamentals plants. For application, Thiophanate-methyl is formulated into wettable powders containing 50 and 70% active ingredient.
[References]

  1. https://apvma.gov.au
  2. https://www.epa.gov
  3. https://sitem.herts.ac.uk
  4. http://www.inchem.org
  5. Terry R Roberts, David H Hutson, Philip W Lee, Peter H Nicholls, and Jack R Plimmer, Metabolic Pathways of Agrochemicals: Part 2: Insecticides and Fungicides, 1999, ISBN 978-0-85404-499-3
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