| Identification | More | [Name]
1,2,3,4,5-Pentamethylcyclopentadiene | [CAS]
4045-44-7 | [Synonyms]
1,2,3,4,5-pentamethyl-1,3-cyclopentadiene
1,2,3,4,5-PENTAMETHYLCYCLOPENTADIENE
PENTAMETHYLCYCLOPENTADIENE
Cyclopentadiene, 1,2,3,4,5-pentamethyl-
1,2,3,4,5-PENTAMETHYLCYCLOPENTADIENE, 95 %
PENTAMETHYLCYCLOPENTADIENE 98+%
1,2,3,4,5-PENTAMETHYLCYCLOPENTADIENE(MINIMUM90%)
Pentamethylcyclopentadiene,min.98%
1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-
1,2,3,4,5-Pentamethylcyclopenta-1,3-diene
Pentamethylcyclopentadiene, min. 98%
1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene
1,2,3,4,5-Pentamethylcyclopenta-2,4-diene
1,2,3,4,5-Pentamethylcyclopentane-1,3-diene | [EINECS(EC#)]
223-743-4 | [Molecular Formula]
C10H16 | [MDL Number]
MFCD00001354 | [Molecular Weight]
136.23 | [MOL File]
4045-44-7.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to yellowish liquid | [Boiling point ]
58 °C13 mm Hg(lit.)
| [density ]
0.87 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.474(lit.)
| [Fp ]
112 °F
| [storage temp. ]
−20°C
| [form ]
Liquid | [color ]
Clear colorless to yellow-orange, may darken on storage | [Specific Gravity]
0.87 | [Water Solubility ]
Miscible with methanol. dichloromethane and ethyl acetate. Slightly miscible with water. | [Sensitive ]
Light Sensitive | [BRN ]
1849832 | [Stability:]
store cold | [InChI]
InChI=1S/C10H16/c1-6-7(2)9(4)10(5)8(6)3/h6H,1-5H3 | [InChIKey]
WQIQNKQYEUMPBM-UHFFFAOYSA-N | [SMILES]
C1(C)C(C)C(C)=C(C)C=1C | [CAS DataBase Reference]
4045-44-7(CAS DataBase Reference) | [NIST Chemistry Reference]
1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-(4045-44-7) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS02 | [Signal word ]
Warning | [Hazard statements ]
H226 | [Precautionary statements ]
P210-P233-P240-P241-P242-P243 | [Risk Statements ]
R10:Flammable. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 3295 3/PG 3
| [WGK Germany ]
3
| [F ]
9-23 | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29021990 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Flam. Liq. 3 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to yellowish liquid | [Uses]
1,2,3,4,5-Pentamethylcyclopentadiene serves as a precursor to the ligand 1,2,3,4,5-pentamethylcyclopentadienyl. It is used as a growth modifier chemical, during metal organic chemical vapor deposition of iron from iron pentacarbonyl. It is used as a ligand in "one-pot" iridium-catalyzed transformation of alcohols to amides. Further, it acts as an electron mediator in the regeneration process of nicotinamide adenine dinucleotide. In addition to this, it undergoes radical cation catalyzed cycloaddition reaction with allenes to get Diels-Alder product. | [General Description]
Mechanism of the Diels-Alder reaction of paramagneticendohedral metallofullerene and 1,2,3,4,5-pentamethylcyclopentadiene has been studied. Three-step large-scale preparation of 1,2,3,4,5-pentamethylcyclopentadiene has been reported. Reaction of 1,2,3,4,5-pentamethylcyclopentadiene (HCp*) with actinide ions in gas phase has been investigated by laser ablation mass spectrometry. It undergoes radical cation catalyzed cycloaddition with electron rich allenes to form Diels-Alder product. |
| Spectrum Detail | Back Directory | [Spectrum Detail]
1,2,3,4,5-Pentamethylcyclopentadiene(4045-44-7)MS
1,2,3,4,5-Pentamethylcyclopentadiene(4045-44-7)1HNMR
1,2,3,4,5-Pentamethylcyclopentadiene(4045-44-7)13CNMR
1,2,3,4,5-Pentamethylcyclopentadiene(4045-44-7)IR1
1,2,3,4,5-Pentamethylcyclopentadiene(4045-44-7)Raman
|
| Well-known Reagent Company Product Information | Back Directory | [Acros Organics]
1,2,3,4,5-Pentamethylcyclopentadiene, 95%(4045-44-7) | [Alfa Aesar]
1,2,3,4,5-Pentamethylcyclopentadiene, 94%(4045-44-7) | [Sigma Aldrich]
4045-44-7(sigmaaldrich) | [TCI AMERICA]
1,2,3,4,5-Pentamethylcyclopentadiene,>93.0%(GC)(4045-44-7) |
|
| Company Name: |
Mascot I.E. Co., Ltd Gold
|
| Telephone: |
0519-85010339 13584504415 |
| Website: |
http://www.mascot-ie.com/ |
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|