| Identification | More | [Name]
3-Pyrrolidinol | [CAS]
40499-83-0 | [Synonyms]
3-HYDROXYPYRROLIDINE
3-HYDROXYPYRROLINE
3-PYRROLIDINOL
DL-3-HYDROXYPYRROLIDINE
DL-3-PYRROLIDINOL
Pyrrolidin-3-ol
3-pyrrolidinol (DL)
3-PYRROLIDINOL FREE BASE
Pyrrolidine-3-ol | [EINECS(EC#)]
254-944-5 | [Molecular Formula]
C4H9NO | [MDL Number]
MFCD00005256 | [Molecular Weight]
87.12 | [MOL File]
40499-83-0.mol |
| Chemical Properties | Back Directory | [Boiling point ]
108-110 °C8 mm Hg(lit.) | [density ]
1.076 g/mL at 20 °C(lit.)
| [refractive index ]
n20/D 1.49(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [form ]
Liquid | [pka]
14.91±0.20(Predicted) | [color ]
Clear colorless to yellow | [BRN ]
102542 | [InChI]
1S/C4H9NO/c6-4-1-2-5-3-4/h4-6H,1-3H2 | [InChIKey]
JHHZLHWJQPUNKB-UHFFFAOYSA-N | [SMILES]
OC1CCNC1 | [CAS DataBase Reference]
40499-83-0(CAS DataBase Reference) | [NIST Chemistry Reference]
3-Pyrrolidinol(40499-83-0) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37:Wear suitable gloves . | [WGK Germany ]
3
| [F ]
10-34 | [HS Code ]
29339900 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Purification Methods]
The (±)-isomer is purified by repeated distillation ( b 102-104o/12mm, 108-110o/18mm), and the (±)-picrate crystallises from EtOH with m 140-141o. The R(+)-enantiomer has b 70o/0.6mm and [] D +5.6o (c 3.63, MeOH). Its hydrochloride has a negative rotation and its dimethiodide has m 230o and [] 24 -8.02o. [Suyama & Kanno Yakugaku Zasshi (J Pharm Soc Japan) 85 531 1965, Uno et al. J Heterocycl Chem 24 1025 1987, Flanagan & Joullie Heterocycles 26 2247 1987, Beilstein 21 III/IV 44.] |
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