| Identification | More | [Name]
2,2,2-TRIFLUOROETHYL TRIFLUOROACETATE | [CAS]
407-38-5 | [Synonyms]
2,2,2-TRIFLUOROETHYL TRIFLUOROACETATE
TRIFLUOROACETIC ACID 2,2,2-TRIFLUOROETHYL ESTER
aceticacid,trifluoro-,2,2,2-trifluoroethylester
CF3C(O)OCH2CF3
ethanol,2,2,2-trifluoro-,trifluoroacetate
Trifluoroacetic acid trifluoroethyl ester
2,2,2-TRIFLUOROETHYL TRIFLUOROACETATE, 9 9%
Trifluoroethyl trifluoroacetate.
2,2,2-Trifluoroethyl trifluoroacetate 98%
2,2,2-Trifluoroethyltrifluoroacetate98% | [EINECS(EC#)]
206-985-5 | [Molecular Formula]
C4H2F6O2 | [MDL Number]
MFCD00000418 | [Molecular Weight]
196.05 | [MOL File]
407-38-5.mol |
| Chemical Properties | Back Directory | [Appearance]
CLEAR COLOURLESS LIQUID | [Melting point ]
-65 °C
| [Boiling point ]
55 °C(lit.)
| [density ]
1.464 g/mL at 25 °C(lit.)
| [vapor pressure ]
3.34 psi ( 20 °C)
| [refractive index ]
n20/D 1.277(lit.)
| [Fp ]
32 °F
| [storage temp. ]
Flammables area | [solubility ]
soluble in Chloroform | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Specific Gravity]
1.464 | [BRN ]
1783427 | [InChI]
InChI=1S/C4H2F6O2/c5-3(6,7)1-12-2(11)4(8,9)10/h1H2 | [InChIKey]
ZKUJOCJJXCPCFS-UHFFFAOYSA-N | [SMILES]
C(OCC(F)(F)F)(=O)C(F)(F)F | [CAS DataBase Reference]
407-38-5(CAS DataBase Reference) | [EPA Substance Registry System]
2,2,2-Trifluoroethyl 2,2,2-trifluoroacetate (407-38-5) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS02,GHS05 | [Signal word ]
Danger | [Hazard statements ]
H225-H314 | [Precautionary statements ]
P210-P233-P240-P280-P303+P361+P353-P305+P351+P338 | [Hazard Codes ]
F,C | [Risk Statements ]
R11:Highly Flammable.
R34:Causes burns. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2924 3/PG 2
| [WGK Germany ]
3
| [Hazard Note ]
Flammable/Corrosive | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29159000 |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
2,2,2-Trifluoroethanol-->Trifluoroacetic acid | [Preparation Products]
Ethyl 2-methyl-4,4,4-trifluoroacetoacetate-->N,N-Diethyl-2,2,2-trifluoroacetamide-->4,4,4-Trifluoro-1-(2-furyl)-1,3-butanedione-->4,4,4-Trifluoro-1-(2-bromophenyl)-1,3-butanedione |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR COLOURLESS LIQUID | [Uses]
2,2,2-Trifluoroethyl trifluoroacetate has been used in the preparation of dimethyl (3,3,3-trifluoro-2,2-dihydroxypropyl)phosphonate. | [General Description]
The molecular structure of 2,2,2-trifluoroethyl trifluoroacetate has been determined in the gas-phase from electron-diffraction data supplemented by ab initio (MP2) and DFT calculations. Hydrogenation of 2,2,2-trifluoroethyl trifluoroacetate catalyzed by anionic tris-phosphine ruthenium hydride complex has been reported. | [Purification Methods]
2,2,2-Trifluoroethyl trifluoroacetate is purified by distillation from calcium hydride at atmospheric pressure.
| [storage]
2,2,2-Trifluoroethyl trifluoroacetate can be adequately dried by simple distillation and can be stored under argon over 4 Angstrom molecular sieves.
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