ChemicalBook--->CAS DataBase List--->461-87-0

461-87-0

461-87-0 Structure

461-87-0 Structure
IdentificationMore
[Name]

2-Fluoro-4-methylpyridine
[CAS]

461-87-0
[Synonyms]

2-FLUORO-4-METHYLPYRIDINE
2-FLUORO-4-PICOLINE
2-FLUORO-4-METHYLPYRIDINE 98%
2-Fluoro-4-methylpyridine/2-Fluoro-4-Picoline
2-Fluoro-4-methylpyridine97%
2-FLUORO-4-METHYLPYRIDINE, 99+%
2-FLUORO-4-PICOLINE 2-FLUORO-4-METHYLPYRIDINE
4-methyl-2-fluoropyridine
2-Fluoro-4-mehtylpyridine
[EINECS(EC#)]

625-585-5
[Molecular Formula]

C6H6FN
[MDL Number]

MFCD00041224
[Molecular Weight]

111.12
[MOL File]

461-87-0.mol
Chemical PropertiesBack Directory
[Appearance]

Clear colourless to light yellow liquid
[Boiling point ]

160-161 °C (lit.)
[density ]

1.078 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.472(lit.)
[Fp ]

>230 °F
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

Liquid
[pka]

0.24±0.10(Predicted)
[color ]

Colorless to pale yellow
[Specific Gravity]

1.078
[BRN ]

107086
[InChI]

1S/C6H6FN/c1-5-2-3-8-6(7)4-5/h2-4H,1H3
[InChIKey]

ZBFAXMKJADVOGH-UHFFFAOYSA-N
[SMILES]

Cc1ccnc(F)c1
[CAS DataBase Reference]

461-87-0(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

1993
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29333990
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

2-Fluoropyridine-4-carboxaldehyde-->(2-Fluoro-pyridin-4-yl)-hydrazine-->Methyl 2-Fluoroisonicotinate-->2-Methyl-2-(4-methylpyridin-2-yl)propanenitrile
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Fluoro-4-methylpyridine(461-87-0).msds
Hazard InformationBack Directory
[Chemical Properties]

Clear colourless to light yellow liquid
[Uses]

2-Fluoro-4-methylpyridine may be used in the preparation of:
  • 2-Fluoro-4-(iodomethyl)pyridine
  • 4-(4-fluorophenyl)-5-(2-fluoropyridin-4-yl)-1,3-dihydroimidazol-2-thione
  • 2-fluoro-4-pyridinemethanol
  • 2-fluoro-4-pyridinemethanol, 4-methylbenzenesulfonate
  • 10,10-bis[(2-fluoro-4-pyridinyl)methyl]-9(10H)-anthracenone
  • 2-fluoro-3-iodo-5-methylpyridine
  • 2-fluoro-4-pyridinecarboxylic acid

[General Description]

2-Fluoro-4-methylpyridine, also known as 2-fluoro-4-picoline, can be prepared based on Talik′s procedure from 2-amino-5-methylpyridine via diazotization. The effect of substituents on spectral properties of 2-fluoro-6-methylpyridine has been investigated based on 13C NMR, UV and IR spectral data.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Fluoro-4-methylpyridine(461-87-0)MS
2-Fluoro-4-methylpyridine(461-87-0)1HNMR
2-Fluoro-4-methylpyridine(461-87-0)13CNMR
2-Fluoro-4-methylpyridine(461-87-0)IR1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

2-Fluoro-4-methylpyridine, 98%(461-87-0)
[Sigma Aldrich]

461-87-0(sigmaaldrich)
[TCI AMERICA]

2-Fluoro-4-picoline,>98.0%(GC)(461-87-0)
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