ChemicalBook--->CAS DataBase List--->407-22-7

407-22-7

407-22-7 Structure

407-22-7 Structure
IdentificationMore
[Name]

2-Fluoro-6-methylpyridine
[CAS]

407-22-7
[Synonyms]

2-FLUORO-6-METHYLPYRIDINE
2-FLUORO-6-PICOLINE
6-FLUORO-2-PICOLINE
Pyridine, 2-fluoro-6-methyl-
2-FLUORO-6-METHYLPYRIDINE 98%
2-Fluoro-6-methylpyridine/2-Fluoro-6-Picoline
2-Fluoro-6-methylpyridine98%
6-methyl-2-fluoropyridine
[EINECS(EC#)]

206-980-8
[Molecular Formula]

C6H6FN
[MDL Number]

MFCD00041226
[Molecular Weight]

111.12
[MOL File]

407-22-7.mol
Chemical PropertiesBack Directory
[Boiling point ]

140-141 °C (lit.)
[density ]

1.077 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.47(lit.)
[Fp ]

152 °F
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

clear liquid
[pka]

0.29±0.10(Predicted)
[color ]

Colorless to Light orange to Yellow
[Specific Gravity]

1.07
[Detection Methods]

HPLC
[BRN ]

107084
[InChIKey]

UDMNVTJFUISBFD-UHFFFAOYSA-N
[CAS DataBase Reference]

407-22-7(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Fluoro-6-methylpyridine(407-22-7)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi,F
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

1993
[WGK Germany ]

3
[Hazard Note ]

Flammable/Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29333990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium nitrite-->Fluoroboric acid-->2-Amino-6-methylpyridine
[Preparation Products]

2-Fluoro-6-formylpyridine
Hazard InformationBack Directory
[Chemical Properties]

liquid
[Uses]

2-Fluoro-6-methylpyridine may be used in the preparation of:
  • 2-fluoro-6-pyridinecarboxylic acid
  • 2,2′-[1-(6-methylpyridin-2-yl)ethane-1,1-diyl]dipyridine
  • 2-fluoropyridine-6-aldoxime
  • 2-fluoro-6-(dibromomethyl)pyridine

[Synthesis Reference(s)]

Tetrahedron, 52, p. 23, 1996 DOI: 10.1016/0040-4020(95)00867-8
[General Description]

2-Fluoro-6-methylpyridine, also known as 2-fluoro-6-picoline, can be prepared via diazotization of 2-amino-6-methylpyridine in hydrogen fluoride containing 40% pyridine solution. The effect of substituents on spectral properties of 2-fluoro-6-methylpyridine has been investigated based on 13C NMR, UV and IR spectral data.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Fluoro-6-methylpyridine(407-22-7)1HNMR
2-Fluoro-6-methylpyridine(407-22-7)IR
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

2-Fluoro-6-methylpyridine, 98%(407-22-7)
[Sigma Aldrich]

407-22-7(sigmaaldrich)
[TCI AMERICA]

6-Fluoro-2-picoline,>95.0%(GC)(407-22-7)
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