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50479-11-3

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50479-11-3 Structure

50479-11-3 Structure
IdentificationBack Directory
[Name]

[3-(ETHOXYCARBONYL)PROPYL]TRIPHENYLPHOSPHONIUM BROMIDE
[CAS]

50479-11-3
[Synonyms]

NSC 269919
RARECHEM FH KO 0044
(3-(ethoxycarbonyl)propyl)triphenyl-phosphonium B
(4-Ethoxy-4-oxobutyl)triphenylphosphonium bromide
(4-ethoxy-4-oxobutyl)-triphenylphosphanium,bromide
[3-(ETHOXYCARBONYL)PROPYL]TRIPHENYLPHOSPHONIUM BROMIDE
(3-Ethoxycarbonylpropyl)triphenylphosphoniumbromide,97%
[4-Ethoxy-4-oxo(but-1-yl)]tris(phenyl)phosphonium bromide
[3-(Ethoxycarbonyl)propyl]triphenylphosphonium bromide 97%
PhosphoniuM, (4-ethoxy-4-oxobutyl)triphenyl-, broMide (1:1)
[3-(Ethoxycarbonyl)prop-1-yl]tris(phenyl)phosphonium bromide
[3-(Ethoxycarbonyl)propyl]triphenylphosphonium bromide, 97 % min.
[Molecular Formula]

C24H26BrO2P
[MDL Number]

MFCD00274610
[MOL File]

50479-11-3.mol
[Molecular Weight]

457.34
Chemical PropertiesBack Directory
[Appearance]

White powder
[Melting point ]

165-167 °C(lit.)
[storage temp. ]

Refrigerator (+4°C)
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Solid
[color ]

White to Off-White
[Stability:]

Hygroscopic
[InChI]

1S/C24H26O2P.BrH/c1-2-26-24(25)19-12-20-27(21-13-6-3-7-14-21,22-15-8-4-9-16-22)23-17-10-5-11-18-23;/h3-11,13-18H,2,12,19-20H2,1H3;1H/q+1;/p-1
[InChIKey]

JPZMNVPVVYVXAD-UHFFFAOYSA-M
[SMILES]

[Br-].CCOC(=O)CCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
Hazard InformationBack Directory
[Chemical Properties]

White powder
[Uses]

Reactant for:
  • Asymmetric synthesis of antihypercholesterolemic ezetimibe via Wittig reaction
  • Wittig reactions
[reaction suitability]

reaction type: C-C Bond Formation
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HS Code ]

29310099
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Spectrum DetailBack Directory
[Spectrum Detail]

[3-(ETHOXYCARBONYL)PROPYL]TRIPHENYLPHOSPHONIUM BROMIDE(50479-11-3)1HNMR
[3-(ETHOXYCARBONYL)PROPYL]TRIPHENYLPHOSPHONIUM BROMIDE(50479-11-3)IR
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