| Identification | Back Directory | [Name]
[3-(ETHOXYCARBONYL)PROPYL]TRIPHENYLPHOSPHONIUM BROMIDE | [CAS]
50479-11-3 | [Synonyms]
NSC 269919
RARECHEM FH KO 0044
(3-(ethoxycarbonyl)propyl)triphenyl-phosphonium B
(4-Ethoxy-4-oxobutyl)triphenylphosphonium bromide
(4-ethoxy-4-oxobutyl)-triphenylphosphanium,bromide
[3-(ETHOXYCARBONYL)PROPYL]TRIPHENYLPHOSPHONIUM BROMIDE
(3-Ethoxycarbonylpropyl)triphenylphosphoniumbromide,97%
[4-Ethoxy-4-oxo(but-1-yl)]tris(phenyl)phosphonium bromide
[3-(Ethoxycarbonyl)propyl]triphenylphosphonium bromide 97%
PhosphoniuM, (4-ethoxy-4-oxobutyl)triphenyl-, broMide (1:1)
[3-(Ethoxycarbonyl)prop-1-yl]tris(phenyl)phosphonium bromide
[3-(Ethoxycarbonyl)propyl]triphenylphosphonium bromide, 97 % min. | [Molecular Formula]
C24H26BrO2P | [MDL Number]
MFCD00274610 | [MOL File]
50479-11-3.mol | [Molecular Weight]
457.34 |
| Chemical Properties | Back Directory | [Appearance]
White powder | [Melting point ]
165-167 °C(lit.)
| [storage temp. ]
Refrigerator (+4°C) | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Solid | [color ]
White to Off-White | [Stability:]
Hygroscopic | [InChI]
1S/C24H26O2P.BrH/c1-2-26-24(25)19-12-20-27(21-13-6-3-7-14-21,22-15-8-4-9-16-22)23-17-10-5-11-18-23;/h3-11,13-18H,2,12,19-20H2,1H3;1H/q+1;/p-1 | [InChIKey]
JPZMNVPVVYVXAD-UHFFFAOYSA-M | [SMILES]
[Br-].CCOC(=O)CCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3 |
| Hazard Information | Back Directory | [Chemical Properties]
White powder | [Uses]
Reactant for:
- Asymmetric synthesis of antihypercholesterolemic ezetimibe via Wittig reaction
- Wittig reactions
| [reaction suitability]
reaction type: C-C Bond Formation |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-36 | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [HS Code ]
29310099 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
|
|