ChemicalBook--->CAS DataBase List--->814-29-9

814-29-9

814-29-9 Structure

814-29-9 Structure
IdentificationMore
[Name]

TRI-N-BUTYLPHOSPHINE OXIDE
[CAS]

814-29-9
[Synonyms]

TRIBUTYLPHOSPHINE OXIDE
TRI-N-BUTYLPHOSPHINE OXIDE
1-(Dibutyl-phosphinoyl)-butane
tributylfosfinoxid
tributyl-phosphineoxid
tris(1-butyl)phosphineoxide
trisbutylphosphineoxide
Tri-n-butylphosphineoxide,97%
Phosphine oxide, tributyl-
HISHICOLIN PO-4
BUTYLPHOS
[EINECS(EC#)]

212-394-3
[Molecular Formula]

C12H27OP
[MDL Number]

MFCD00002082
[Molecular Weight]

218.32
[MOL File]

814-29-9.mol
Chemical PropertiesBack Directory
[Appearance]

white crystalline powder
[Melting point ]

64-69 °C(lit.)
[Boiling point ]

150 °C1.5 mm Hg(lit.)
[density ]

0.8480 g/cm3
[Fp ]

150°C/1mm
[storage temp. ]

2-8°C
[solubility ]

55.7g/l
[form ]

solid
[color ]

White to Almost white
[Water Solubility ]

Soluble in water (56 g/L at 20°C).
[Sensitive ]

Hygroscopic
[BRN ]

1761977
[InChI]

InChI=1S/C12H27OP/c1-4-7-10-14(13,11-8-5-2)12-9-6-3/h4-12H2,1-3H3
[InChIKey]

MNZAKDODWSQONA-UHFFFAOYSA-N
[SMILES]

P(=O)(CCCC)(CCCC)CCCC
[CAS DataBase Reference]

814-29-9(CAS DataBase Reference)
[EPA Substance Registry System]

Tributylphosphine oxide (814-29-9)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 1759 8/PG 2
[WGK Germany ]

3
[RTECS ]

SZ1575000
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29319090
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Skin Corr. 1B
Hazard InformationBack Directory
[Chemical Properties]

white crystalline powder
[Uses]

Oseltamivir (O701000) impurity.
[Synthesis Reference(s)]

Synthesis, p. 114, 1975
Tetrahedron Letters, 31, p. 3359, 1990 DOI: 10.1016/S0040-4039(00)89065-6
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
Spectrum DetailBack Directory
[Spectrum Detail]

TRI-N-BUTYLPHOSPHINE OXIDE(814-29-9)MS
TRI-N-BUTYLPHOSPHINE OXIDE(814-29-9)1HNMR
TRI-N-BUTYLPHOSPHINE OXIDE(814-29-9)13CNMR
TRI-N-BUTYLPHOSPHINE OXIDE(814-29-9)IR1
TRI-N-BUTYLPHOSPHINE OXIDE(814-29-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Tributylphosphine oxide, 98%(814-29-9)
[Alfa Aesar]

Tri-n-butylphosphine oxide, 97%(814-29-9)
[Sigma Aldrich]

814-29-9(sigmaaldrich)
[TCI AMERICA]

Tributylphosphine Oxide,>90.0%(GC)(814-29-9)
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