ChemicalBook--->CAS DataBase List--->52509-14-5

52509-14-5

52509-14-5 Structure

52509-14-5 Structure
IdentificationMore
[Name]

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide
[CAS]

52509-14-5
[Synonyms]

(1,3-DIOXOLAN-2-YLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
(1,3-DIOXOLANE-2-YL METHYL) TRIPHENYL PHOSPHONIUM BROMIDE
LABOTEST-BB LT00233112
TRIPHENYL-1,3-DIOXOLAN-2-YLMETHYL-PHOSPHONIUM BROMIDE
2-(1,3)-DIOXOLANE-2-YL-METHYLTRIPHENYLPHOSPHONIUM BROMIDE
Phosphonium, (1,3-dioxolan-2-ylmethyl)triphenyl-, bromide
(1,3-DIOXOLAN-2-YLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE 98%
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98 %
1,3-Dioxolan-2-ylmethyl-triphenylphosphanium bromide
Triphenyl(1,3-dioxolane-2-ylmethyl)phosphonium·bromide
[EINECS(EC#)]

257-977-3
[Molecular Formula]

C22H22BrO2P
[MDL Number]

MFCD00011966
[Molecular Weight]

429.29
[MOL File]

52509-14-5.mol
Chemical PropertiesBack Directory
[Appearance]

white to light brown granular powder
[Melting point ]

193-195 °C(lit.)
[storage temp. ]

Store below +30°C.
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Powder or Crystals
[color ]

White to light brown
[Water Solubility ]

Soluble in water (20°C).
[Sensitive ]

Hygroscopic
[InChIKey]

FRHRVQQUICVJDG-UHFFFAOYSA-M
[CAS DataBase Reference]

52509-14-5(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[HS Code ]

29329970
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide(52509-14-5).msds
Hazard InformationBack Directory
[Chemical Properties]

white to light brown granular powder
[Uses]

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium Bromide is used as a reactant in the synthesis of ketolides methyloxoerythromycins with antibacterial activity as highly potent against macrolide-resistant and susceptible respiratory pathogens.
[Purification Methods]

Wash the crystals with Et2O, dry them in a vacuum and recrystallise them from CH2Cl2/dry Et2O to give prisms m 172-174o, which is raised to 191.5-193o on drying at 56o/0.5mm. [Cresp et al. J Chem Soc, Perkin Trans 1 37 1974.]
Spectrum DetailBack Directory
[Spectrum Detail]

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide(52509-14-5)1HNMR
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide(52509-14-5)Raman
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide(52509-14-5)IR
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide(52509-14-5)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98%(52509-14-5)
[Alfa Aesar]

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98%(52509-14-5)
[Sigma Aldrich]

52509-14-5(sigmaaldrich)
[TCI AMERICA]

(1,3-Dioxolan-2-yl)methyltriphenylphosphonium Bromide,>96.0%(T)(52509-14-5)
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