ChemicalBook--->CAS DataBase List--->5336-08-3

5336-08-3

5336-08-3 Structure

5336-08-3 Structure
IdentificationMore
[Name]

D(+)-Ribonic acid gamma-lactone
[CAS]

5336-08-3
[Synonyms]

(3R,4S,5R)-3,4-DIHYDROXY-5-HYDROXYMETHYL-DIHYDRO-FURAN-2-ONE
D-(+)-RIBONIC ACID GAMMA-LACTON
D(+)-RIBONIC ACID GAMMA-LACTONE
D-(+)-RIBONIC ACID G-LACTONE
D-(+)-RIBONIC GAMMA-LACTONE
D(+)-RIBONO-1,4-LACTONE
D-RIBONO-1,4-LACTONE
D-(+)-RIBONO-GAMMA-LACTONE
D-RIBONOLACTONE
D-(+)-RIBONONE-1.4-LACTONE
D-RIBOSE-LACTONE
RIBONIC ACID-GAMMA-LACTONE, D-(+)-
RIBONOLACTONE
D-Ribo-1,4-pentonolactone
D-Ribopentono-1,4-lactone
gamma-Lactone of ribonic acid
Ribono-gamma-lactone
Riborolactone
D(+)-Ribonic acid-γ-lactone
D-RIBONO-1,4-LACTONE(D-(+)-RIBONIC ACID GAMMA-LACTONE)
[EINECS(EC#)]

226-256-5
[Molecular Formula]

C5H8O5
[MDL Number]

MFCD00063241
[Molecular Weight]

148.11
[MOL File]

5336-08-3.mol
Chemical PropertiesBack Directory
[Appearance]

White Crystalline Solid
[Melting point ]

85-87 °C(lit.)
[alpha ]

18 º (c=5, H2O)
[Boiling point ]

188.68°C (rough estimate)
[density ]

1.2336 (rough estimate)
[refractive index ]

18 ° (C=1, H2O)
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

H2O: 0.1 g/mL, clear
[form ]

Powder
[pka]

12.10±0.60(Predicted)
[color ]

White to Pale Yellow
[optical activity]

[α]24/D +18°, c = 1 in H2O
[Water Solubility ]

soluble
[Usage]

Important chiral synthon
[BRN ]

82057
[Stability:]

Stable
[CAS DataBase Reference]

5336-08-3(CAS DataBase Reference)
[NIST Chemistry Reference]

D-(+)-Ribonic acid gamma-lactone(5336-08-3)
Safety DataBack Directory
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[HS Code ]

29322090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

RIBONIC ACID
[Preparation Products]

1-deoxy-1-(6-phenylazo-3,4-xylidino)-D-ribitol-->2,3-O-Isopropylidene-D-lyxono-1,4-lactone-->(S)-5-Hydroxymethyldihydrofuran-2-one-->2 3-O-CYCLOHEXYLIDENE-D-RIBONIC ACID-->5-BROMO-5-DEOXY-2,3-O-ISOPROPYLIDENE-D-RIBONOLACTONE-->2,3-O-Isopropylidene-D-ribonic gamma-lactone
Hazard InformationBack Directory
[Chemical Properties]

White Crystalline Solid
[Uses]

A sugar lactone as inhibitor of β-galactosidase of E. coli.
[Uses]

Important chiral synthon
[Definition]

ChEBI: A five-membered form of ribonolactone having D-configuration.
[Purification Methods]

Purify D-(+)-ribonic acid--lactone by recrystallisation from EtOAc. The tribenzoate has m 54-56o (from AcOH), [] D 25 +27o (c 2.37, Me2NCHO), and the 3,5-O-benzylidene derivative has m 230-231.5o (needles from Me2CO-pet ether) and [] D 25 -177o (CHCl3). [Chen & Joulié J Org Chem 49 2168 1984, Zinner & Voigt J Carbohydr Research 7 38 1968.]
Spectrum DetailBack Directory
[Spectrum Detail]

D(+)-Ribonic acid gamma-lactone(5336-08-3)MS
D(+)-Ribonic acid gamma-lactone(5336-08-3)1HNMR
D(+)-Ribonic acid gamma-lactone(5336-08-3)IR1
D(+)-Ribonic acid gamma-lactone(5336-08-3)IR2
D(+)-Ribonic acid gamma-lactone(5336-08-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

D(+)-Ribonic acid gamma-lactone, 96%(5336-08-3)
[Sigma Aldrich]

5336-08-3(sigmaaldrich)
[TCI AMERICA]

D-(+)-Ribono-1,4-lactone,>95.0%(GC)(5336-08-3)
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