Identification | More | [Name]
ZINC TRIFLUOROMETHANESULFONATE | [CAS]
54010-75-2 | [Synonyms]
TRIFLUOROMETHANESULFONIC ACID ZINC SALT ZINC TRIFLATE ZINC TRIFLUOROMETHANESULFONATE ZINC TRIFLUOROMETHANESULPHONATE trifluoro-methanesulfonicacizincsalt Zinctrifluoromethanesulfonate,min.98%(Zinctriflate) Methanesulfonic acid, trifluoro-, zinc salt trifluoromethanesulfonic acid zinc(ii) salt zinc(ii) triflate Zinc trifluoromethanesulphonate 98% Zinctrifluoromethanesulphonate98% ZINC TRIFLUOROMETHANESULFONATE (ZINC TRIFLATE) Trifluoromethanesulfonic acid zinc salt, Zinc triflate Bis(trifluoromethanesulfonic acid)zinc salt Bis(trifluoromethylsulfonyloxy) zinc Zinc bis(trifluoromethanesulfonate) | [EINECS(EC#)]
258-922-6 | [Molecular Formula]
C2F6O6S2Zn | [MDL Number]
MFCD00013229 | [Molecular Weight]
363.53 | [MOL File]
54010-75-2.mol |
Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
3-10 | [Hazard Note ]
Irritant/Hygroscopic | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29049090 |
Hazard Information | Back Directory | [Chemical Properties]
white to light-grey powder | [Uses]
Zinc trifluoromethanesulfonate acts as a catalyst for the preparation of dithioketals. It is used as a Lewis acid catalyst in silylation reactions. It is also used as a catalyst for greener amine synthesis by reductive amination with hydrogen gas. | [General Description]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. | [Purification Methods]
It should be dried at 125o for 2hours at 3mm before use. It is soluble in CH2Cl2 but insoluble in pet ether. [Corey & Shimoji Tetrahedron Lett 24 169 1983.] |
Questions And Answer | Back Directory | [Reaction]
- Catalyst for the addition of acetylenes to carbonyls and nitrones.
- Claisen rearrangement.
- Catalyst for the enantioselective Henry and Aza-Henry reactions.
- Pd-catalyzed hydroalkylation of styrenes with zinc reagents.
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