ChemicalBook--->CAS DataBase List--->56-35-9

56-35-9

56-35-9 Structure

56-35-9 Structure
IdentificationMore
[Name]

Bis(tributyltin) oxide
[CAS]

56-35-9
[Synonyms]

BIS(TRIBUTYLTIN) OXIDE
BIS(TRI-N-BUTYLTIN) OXIDE
CAR-BAN(R)
HBD
HEXABUTYLDISTANNOXANE
OXYBIS(TRIBUTYLTIN)
TBTO
TBTO(R)
TBTO(TM)
T-O-BIOSTAT(R)
TRIBUTYLTIN OXIDE
'TRIBUTYLTIN OXIDE'
1,1,1,3,3,3-Hexabutyldistannoxane
5,5,7,7-tetrabutyl-6-oxa-7-distannaundecane
6-Oxa-5,7-distannaundecane, 5,5,7,7-tetrabutyl-
acetotbto
Biomet
Biomet 66
BioMet SRM
Biomet TBTO
[EINECS(EC#)]

200-268-0
[Molecular Formula]

C24H54OSn2
[MDL Number]

MFCD00009418
[Molecular Weight]

596.1
[MOL File]

56-35-9.mol
Chemical PropertiesBack Directory
[Description]

TBTO (bis(tri-n-butyltin)oxide) appears as thin, colourless to pale yellow, flammable and combustible liquid. It is soluble in organic solvents. TBTO, or bis(tri-n-butyltin)oxide, is an organotin compound used as a biocide, fungicide, and molluscicide. Uses of tributyltin also include as an anti-fouling chemical in marine paints for boats, anti-fungal agent in textiles and industrial water systems, in cooling tower and refrigeration water systems, wood pulp preservative in paints and paper mill systems, inner surfaces of cardboard, and in the manufacturing processes of leather goods, textiles, wood, plastics, and mothproof stored garments. In fact, TBT compounds are considered the most hazardous of all tin compounds.
[Appearance]

Clear colorless liquid
[Melting point ]

-45°C
[Boiling point ]

180 °C2 mm Hg(lit.)
[density ]

1.17 g/mL at 25 °C(lit.)
[vapor pressure ]

<0.01 mm Hg ( 25 °C)
[refractive index ]

n20/D 1.486(lit.)
[Fp ]

>230 °F
[storage temp. ]

+4°C
[solubility ]

Chloroform (Soluble), Methanol (Slightly)
[form ]

liquid
[color ]

colorless
[Specific Gravity]

1.170
[Water Solubility ]

INSOLUBLE
[Hydrolytic Sensitivity]

5: forms reversible hydrate
[Sensitive ]

Air & Moisture Sensitive
[BRN ]

745057
[Exposure limits]

ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
[Stability:]

Moisture Sensitive
[Contact allergens]

Tributyl tin oxide is used as an antifouling and biocide agent against fungi, algae, and bacteria, particularly in paints. Sometimes used in chemistry, tributyltin oxide is a strong irritant.
[InChIKey]

APQHKWPGGHMYKJ-UHFFFAOYSA-N
[LogP]

3.840 (est)
[CAS DataBase Reference]

56-35-9(CAS DataBase Reference)
[NIST Chemistry Reference]

Distannoxane, hexabutyl-(56-35-9)
[EPA Substance Registry System]

56-35-9(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless liquid
[Uses]

Bis(tributyltin) Oxide is an organotin compound used as a fungicide and molluscicide, particularly in wood preservation. Bis(tributyltin) Oxide was used as an active component in marine antifouling paints but is not longer used due to its toxicity and is considered a severe marine pollutant.
[General Description]

Clear pale yellow liquid. Toxic by skin absorption or inhalation of vapors. Used as a bactericide, fungicide and chemical intermediate.
[Reactivity Profile]

BIS(TRIBUTYLTIN) OXIDE(56-35-9) may react vigorously with oxidizing agents and with reducing agents.
[Air & Water Reactions]

Insoluble in water.
[Hazard]

Toxic via ingestion and inhalation.
[Health Hazard]

ACUTE/CHRONIC HAZARDS: This material is toxic by ingestion and inhalation and is a skin and eye irritant.
[Fire Hazard]

This chemical is probably combustible.
[Definition]

ChEBI: Tributyltin oxide is an inorganic molecular entity.
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

R21:Harmful in contact with skin.
R25:Toxic if swallowed.
R36/38:Irritating to eyes and skin .
R48/23/25:Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S35:This material and its container must be disposed of in a safe way .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 2788 6.1/PG 2
[WGK Germany ]

3
[RTECS ]

JN8750000
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29310095
[Hazardous Substances Data]

56-35-9(Hazardous Substances Data)
[Toxicity]

LD50 oral in rat: 87mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Magnesium-->1-Chlorobutane-->Tributyltin chloride
[Preparation Products]

4-Nitrophenyl-beta-D-galactopyranoside-->2-Chloro-4-nitrophenyl-alpha-L-fucopyranoside-->TRI-N-BUTYLTIN METHOXIDE-->TRIBUTYLPROPYNYLSTANNANE-->TRIBUTYLPHENYLTIN-->Tributyltin azide-->TRI-N-BUTYLTIN ACETATE-->([1,1'-Biphenyl]-2-yloxy)tributylstannane-->Tributyl(2-methoxyphenyl)stannane-->1,3,5-Tris(tributylstannyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Hexabutyldistannoxane(56-35-9).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Bis(tributyltin) oxide(56-35-9)MS
Bis(tributyltin) oxide(56-35-9)1HNMR
Bis(tributyltin) oxide(56-35-9)13CNMR
Bis(tributyltin) oxide(56-35-9)IR1
Bis(tributyltin) oxide(56-35-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Bis(tri-n-butyltin) oxide, stabilized, 96%(56-35-9)
[Alfa Aesar]

Bis(tri-n-butyltin) oxide, 97%(56-35-9)
[Sigma Aldrich]

56-35-9(sigmaaldrich)
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