ChemicalBook--->CAS DataBase List--->55135-66-5

55135-66-5

55135-66-5 Structure

55135-66-5 Structure
IdentificationMore
[Name]

9-Bromo-9-phenylfluorene
[CAS]

55135-66-5
[Synonyms]

9-BROMO-9-PHENYL-9H-FLUORENE
9-BROMO-9-PHENYLFLUORENE
AKOS 91526
9-Bromo-9-phenylfluorene,97%
[EINECS(EC#)]

628-283-1
[Molecular Formula]

C19H13Br
[MDL Number]

MFCD00075522
[Molecular Weight]

321.21
[MOL File]

55135-66-5.mol
Chemical PropertiesBack Directory
[Appearance]

Yellow Crystalline Solid
[Melting point ]

99-101 °C (lit.)
[Boiling point ]

394.3±41.0 °C(Predicted)
[density ]

1.425±0.06 g/cm3(Predicted)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[Usage]

A bulky amine protecting reagent reported to be 6000 times more stable to acid than the trityl group
[BRN ]

2561445
[InChIKey]

HYQXNCDBSALQLB-UHFFFAOYSA-N
[CAS DataBase Reference]

55135-66-5(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29039930
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Diethyl ether-->Toluene-->Hydrogen bromide-->PHENYLMAGNESIUM BROMIDE-->9-Fluorenone-->9-PHENYLFLUORENE-->9-Phenyl-9-fluorenol-->Acetyl bromide-->Triphenylmethanol-->Bromobenzene
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

9-Bromo-9-phenylfluorene(55135-66-5).msds
Hazard InformationBack Directory
[Chemical Properties]

Yellow Crystalline Solid
[Uses]

9-Bromo-9-phenylfluorene may be used in the preparation of:
  • N-(9-(9-phenylfluorenyl))-L-alaninal
  • N-(9-phenylfluoren-9-yl)-L-serine
  • 1-hydroxypyrazoles priotected at the oxygen atom
[Uses]

A bulky amine protecting reagent reported to be 6000 times more stable to acid than the trityl group
[General Description]

Solvolysis of 9-bromo-9- phenylfluorene has been reported to proceed via limiting SN1 mechanism.
Spectrum DetailBack Directory
[Spectrum Detail]

9-Bromo-9-phenylfluorene(55135-66-5)MS
9-Bromo-9-phenylfluorene(55135-66-5)1HNMR
9-Bromo-9-phenylfluorene(55135-66-5)13CNMR
9-Bromo-9-phenylfluorene(55135-66-5)Raman
9-Bromo-9-phenylfluorene(55135-66-5)IR
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

9-Bromo-9-phenylfluorene, 96%(55135-66-5)
[TCI AMERICA]

9-Bromo-9-phenylfluorene,>96.0%(GC)(55135-66-5)
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