| Identification | More | [Name]
Bromodiphenylmethane | [CAS]
776-74-9 | [Synonyms]
ALPHA-BROMODIPHENYLMETHANE
BENZHYDRYL BROMIDE
BROMODIPHENYLMETHANE
DIPHENYLBROMOMETHANE
DIPHENYLMETHYL BROMIDE
[Bromo(phenyl)methyl]benzene
1,1’-(bromomethylene)bis-benzen
1,1’(Bromomethylene)bisbenzene
Methane, bromodiphenyl-
9,10-Dihydro-4H-Benzo[4,5] Cyclohepta[1,2-B] Thiophene
Benzhydryl bromide, (Bromodiphenylmathane
Bromodiphenylmethane~Diphenylmethyl bromide
N,N-Di(butyl)amino-3-chloropropane
BROMODIPHENYLMETHANE CRYSTALLINE
BenzhydrylBromide,>97%
Bromodiphenyl
Benzene, 1,1-(bromomethylene)bis-
9,10-DIHYDRO-4H-BENZO[4,5]CYCLOHEPTA[1,2-B]THIOPHENE(BROMODIPHENYLMETHANE)
Benzhydryl bromide, Diphenylbromomethane | [EINECS(EC#)]
212-279-8 | [Molecular Formula]
C13H11Br | [MDL Number]
MFCD00000134 | [Molecular Weight]
247.13 | [MOL File]
776-74-9.mol |
| Chemical Properties | Back Directory | [Appearance]
ORANGE-RED TO ORANGE-BROWN LOW MELTING SOLID | [Melting point ]
35-39 °C(lit.)
| [Boiling point ]
184 °C20 mm Hg(lit.)
| [density ]
0,9 g/cm3 | [refractive index ]
1.6290 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
Store below +30°C. | [solubility ]
0.45g/l | [form ]
powder to lump to clear liquid | [color ]
White to cream to yellow to orange to brown crystals or fused solid | [PH]
2 (H2O, 20℃)(saturated aqueous solution) | [Water Solubility ]
Insoluble | [Sensitive ]
Moisture Sensitive | [BRN ]
638544 | [CAS DataBase Reference]
776-74-9(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzene, 1,1'-(bromomethylene)bis-(776-74-9) | [EPA Substance Registry System]
776-74-9(EPA Substance) |
| Questions And Answer | Back Directory | [Uses]
Benzhydryl Bromide is used as a reagent in the synthesis of O-(triazolyl)methyl carbamates as a novel and potent class of fatty acid amide hydrolase (FAAH) inhibitors. |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS05 | [Signal word ]
Danger | [Hazard statements ]
H318-H314 | [Precautionary statements ]
P280-P305+P351+P338-P310-P309-P260-P264-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P405-P501 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns.
R37:Irritating to the respiratory system. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 1770 8/PG 2
| [WGK Germany ]
3
| [RTECS ]
PA5350000 | [F ]
19-21 | [TSCA ]
Yes | [REACH Registrations]
Active | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29036990 | [Safety Profile]
A corrosive, irritating
liquid, When heated to decomposition it
emits toxic fumes of Br-. See also
|
| Hazard Information | Back Directory | [General Description]
DIPHENYLMETHYL BROMIDE(776-74-9) is a white crystalline solid. Melting point 113°F. A lachrymator. In the presence of moisture corrosive to tissue and most metals. | [Reactivity Profile]
Halogenated aliphatic compounds are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. | [Air & Water Reactions]
Insoluble in cold water. Decomposed by hot water to give corrosive hydrobromic acid. | [Health Hazard]
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. | [Fire Hazard]
Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. | [Chemical Properties]
ORANGE-RED TO ORANGE-BROWN LOW MELTING SOLID | [Synthesis]
In a 250mL three-necked flask, 33.6g (0.2mol) of diphenylmethane, 8g (0.2mol) of sodium hydroxide were added and heated to an internal temperature of 95-105 °C. Slowly add bromine 33.6kg (0.21mol) dropwise, dropwise completion, hold at 100-110°C for 3 hou |
|
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
|
| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
|