| Identification | More | [Name]
Methyl 3-(4-hydroxyphenyl)propionate | [CAS]
5597-50-2 | [Synonyms]
3-(4-HYDROXYPHENYL)PROPIONIC ACID METHYL ESTER
3-(4'-HYDROXYPHENYL)-PROPIONIC ACID-OME
3-(4-HYDROXY-PHENYL)-PROPIONIC ACID-OME
4-hydroxy-benzenepropanoic acid methyl ester
METHYL 3-(4-HYDROXYPHENYL)PROPIONATE
METHYL P-HYDROXYHYDROCINNAMATE
4-hydroxy-benzenepropanoicacimethylester
Hydrocinnamic acid, p-hydroxy-, methyl ester
Methyl 3-(4-hydroxyphenyl)propanoate
Methyl 3-(p-hydroxyphenyl)propionate
Methyl 4-hydroxyhydrocinnamate
Propanoic acid, 3-(4-hydroxyphenyl), methyl ester
3-(4-hydroxybenzene)propionic methyl ester
Methyl 4-hydroxyphenylpropionate
METHYL 3-(4-HYDROXYPHENYL)PROPIONATE, 97 %
4-Hydroxyphenylpropionic Acid Methyl Ester
3-(4-HYDROCHLORIDE )PROPIONIC ACID METHYL ESTER
Methyl p-hydroxyphenylpropionate
3-(4-Hydroxyphenyl)propanoic acid methyl ester
4-Hydroxybenzenepropionic acid methyl ester | [Molecular Formula]
C10H12O3 | [MDL Number]
MFCD00071577 | [Molecular Weight]
180.2 | [MOL File]
5597-50-2.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [HS Code ]
29181990 |
| Hazard Information | Back Directory | [Chemical Properties]
white transparent low melting mass | [Uses]
Methyl 3-(4-hydroxyphenyl)propionate may be used in the enzymatic coupling of saccharides to protein. | [Definition]
ChEBI: Methyl 3-(4-hydroxyphenyl)propionate is a methyl ester resulting from the formal condensation of the carboxy group of phloretic acid with methanol. It is a nitrification inhibitor and a plant growth regulator. It has a role as a nitrification inhibitor and a plant growth regulator. It is a member of phenols and a methyl ester. It is functionally related to a phloretic acid. | [General Description]
Methyl 3-(4-hydroxyphenyl)propionate is reported to be responsible for biological nitrification inhibition in sorghum (Sorghum bicolor). | [Synthesis]
General procedure for the synthesis of methyl 4-hydroxyphenylpropionate from methyl 4-hydroxycinnamate: Pd/C (0.1 g) was added to a solution of methyl (E)-3-(4-hydroxyphenyl)acrylate (1.0 g, 5.6 mmol) in ethanol (20 mL). The reaction mixture was stirred vigorously at room temperature under hydrogen atmosphere (1 bar) for 21 hours. Upon completion of the reaction, the suspension was filtered through a diatomaceous earth pad and evaporated to dryness under vacuum to afford the oily product methyl 3-(4-hydroxyphenyl)propionate (1.0 g, 5.6 mmol, 99% yield). The structure of the product was confirmed by 1H NMR (400 MHz, CDCl3): δ 7.07 (ddd, J=8.8,2.8,2.0 Hz, 2H), 6.76 (ddd, J=8.8,2.8,2.0 Hz, 2H), 4.72 (br s, 1H), 3.67 (s, 3H), 2.88 (t, J=7.8 Hz, 2H). 2.60 (t, J=7.8Hz, 2H). | [References]
[1] Journal of Natural Products, 1999, vol. 62, # 1, p. 102 - 106
[2] Patent: EP2745876, 2014, A1. Location in patent: Page/Page column
[3] Patent: US2015/344408, 2015, A1. Location in patent: Paragraph 0413-0415
[4] Journal of Agricultural and Food Chemistry, 2007, vol. 55, # 26, p. 10635 - 10640
[5] Angewandte Chemie - International Edition, 2014, vol. 53, # 30, p. 7785 - 7788 |
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