| Identification | More | [Name]
BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE | [CAS]
56183-63-2 | [Synonyms]
BIS(DI-I-PROPYLAMINO)CHLOROPHOSPHINE
BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE
bis(diisopropylamino)chlorophosphane
Bis-(diisopropylamino)-chlorphosphin
Bis(diisopropylamino)phosphanylchloride
Bis(N,N-diisopropylamino)chlorophosphine
Chlorbis(diisopropylamino)phosphan
Chloro(bis(diisopropylamino))phosphane
chlorobis(diisopropylamino)phosphine
chlorobis(N,N-diisopropyl)phosphoramidite
Chloro-di-N-(diisopropyl)-phosphite
Phosphorigsαure-bis-(N,N-diisopropylamid)-chlorid
Bis(diisopropyamino)chlorophosphine
Bis(di-i-propylamino)chlorophosphine,min.97%
Bis(di-i-propylamino)chlorophosphine, min. 97%
Bis(diisopropilamino)-chlorophosphine
Phosphorodiamidous chloride, N,N,N',N'-tetrakis(1-methylethyl)- | [Molecular Formula]
C12H28ClN2P | [MDL Number]
MFCD00061482 | [Molecular Weight]
266.79 | [MOL File]
56183-63-2.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
100-104 °C(lit.)
| [Boiling point ]
291℃ | [Fp ]
130℃ | [storage temp. ]
Store under inert gas | [form ]
Powder | [pka]
4.50±0.70(Predicted) | [color ]
white to off-white | [Sensitive ]
air sensitive, moisture sensitive | [InChI]
InChI=1S/C12H28ClN2P/c1-9(2)14(10(3)4)16(13)15(11(5)6)12(7)8/h9-12H,1-8H3 | [InChIKey]
FEHUTHGOLLQBNW-UHFFFAOYSA-N | [SMILES]
P(N(C(C)C)C(C)C)(N(C(C)C)C(C)C)Cl | [CAS DataBase Reference]
56183-63-2(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS05 | [Signal word ]
Danger | [Hazard statements ]
H314 | [Precautionary statements ]
P260-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338 | [Hazard Codes ]
C | [Risk Statements ]
R14:Reacts violently with water.
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 1
| [WGK Germany ]
3
| [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29310099 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Skin Corr. 1B |
| Hazard Information | Back Directory | [Description]
Bis(diisopropylamino)chlorophosphine is a white to off-white powder to crystalline organophosphorus compound, mainly used as an organic synthetic raw material or reaction reagent. It can be used in the synthesis of mixed phosphorothioate and methylenephosphine derivatives, etc. It is commonly used in chemical production and laboratory research. | [Chemical Properties]
white to light yellow crystal powde | [Uses]
Bis(diisopropylamino)chlorophosphine has been used in the synthesis of tert-butyl tetraisopropylphosphorodiamidite ligand for palladium-catalyzed Buchwald–Hartwig amination reaction.
It is also can be used to synthesize:
- acyclic N-phosphonio imine catalyst for selective epoxidations
- boryl-substituted methylenephosphonium derivatives
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling |
|
| Company Name: |
Entegris, Inc. Gold
|
| Telephone: |
021-52980362 18121213678 |
| Website: |
https://www.entegris.com |
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|