| Identification | More | [Name]
1-Hydroxy-2,1-benzoxaborolane | [CAS]
5735-41-1 | [Synonyms]
1-HYDROXY-2,1-BENZOXABOROLANE
2-(HYDROXYMETHYL)BENZENEBORONIC ACID CYCLIC MONOESTER
(2-HYDROXYMETHYL)BENZENEBORONIC ACID DEHYDRATE
2-(HYDROXYMETHYL)BENZENEBORONIC ACID HEMIESTER
2-(HYDROXYMETHYL)PHENYLBORONIC ACID CYCLIC MONOESTER
(2-HYDROXYMETHYLPHENYL)BORONIC ACID DEHYDRATE
2-(HYDROXYMETHYL)PHENYLBORONIC ACID, DIHYDRATE
AKOS BRN-0113
1-Hydroxy-2,1-benzoxaborolane~2-(Hydroxymethyl)phenylboronic acid cyclic monoester
2-(HYDROXYMETHYL)PHENYLBORONIC ACID CYC&
1-Hydroxy-1,2-benzoxaborolane
2-(Hydroxymethyl)Phenylboronic
2-(Hydroxymethyl)benzeneboronic acid dehydrate 98%
1-Hydroxy-2,1-benzoxaborolane, Alt cas [87199-14-2]
2-Hydroxymethylphenylboronic acid, dehydrated
2-(HYDROXYMETHYL)BENZENEBORONIC ACID HEMIESTER, 98+%
1,3-Dihydro-1-hydroxy-2,1-benzoxaborole, 2-(Hydroxymethyl)phenylboronic acid hemiester | [Molecular Formula]
C7H7BO2 | [MDL Number]
MFCD01075677 | [Molecular Weight]
133.94 | [MOL File]
5735-41-1.mol |
| Chemical Properties | Back Directory | [Melting point ]
95-100 °C | [Boiling point ]
237.2±43.0 °C(Predicted) | [density ]
1.18±0.1 g/cm3(Predicted) | [storage temp. ]
Keep Cold | [form ]
powder to crystal | [pka]
7.01±0.20(Predicted) | [color ]
White to Almost white | [BRN ]
4333 | [InChI]
InChI=1S/C7H7BO2/c9-8-7-4-2-1-3-6(7)5-10-8/h1-4,9H,5H2 | [InChIKey]
XOQABDOICLHPIS-UHFFFAOYSA-N | [SMILES]
B1(O)C2=CC=CC=C2CO1 | [CAS DataBase Reference]
5735-41-1(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3 | [Hazard Note ]
Irritant/Keep Cold | [HS Code ]
29349990 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
Solid | [Uses]
Oxaboroles and benzoxaboroles are useful substrates to prepare allylic and benzylic alcohols via Suzuki coupling. | [Definition]
ChEBI: 1-hydroxy-2,1-benzoxaborole is a member of the class of benzoxaboroles that is 2,1-benzoxaborole in which the hydrogen attached to the boron atom is replaced by a hydroxy group. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 80, p. 835, 1958 DOI: 10.1021/ja01537a021 |
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