| Identification | More | [Name]
Methyl 2-methyl-3-nitrobenzoate | [CAS]
59382-59-1 | [Synonyms]
3-NITRO-O-TOLUIC ACID METHYL ESTER
METHYL 2-METHYL-3-NITROBENZENECARBOXYLATE
METHYL 2-METHYL-3-NITROBENZOATE
METHYL 3-NITRO-O-TOLUATE
Methyl 2-Methyl-3-Nitro-Benzoatee
3-Nitro-2-methylbenzoic acid methyl ester
3-NITRO-0-TOLUIC ACID METHYL ESTER
3-Nitro-o-toluic acid methyl ester (COOCH3=1)
Methyl 3-nitro-2-methylbenzoate
Benzoic acid, 2-methyl-3-nitro-, methyl ester
Methyl 2-methyl-3-nitrobenzoate, 98+% | [Molecular Formula]
C9H9NO4 | [MDL Number]
MFCD00082564 | [Molecular Weight]
195.17 | [MOL File]
59382-59-1.mol |
| Chemical Properties | Back Directory | [Melting point ]
62-65 °C (lit.) | [Boiling point ]
286.6±20.0 °C(Predicted) | [density ]
1?+-.0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Soluble in methanol. | [form ]
Solid | [color ]
Pale Beige | [BRN ]
1964020 | [InChI]
InChI=1S/C9H9NO4/c1-6-7(9(11)14-2)4-3-5-8(6)10(12)13/h3-5H,1-2H3 | [InChIKey]
CRZGFIMLHZTLGT-UHFFFAOYSA-N | [SMILES]
C(OC)(=O)C1=CC=CC([N+]([O-])=O)=C1C | [CAS DataBase Reference]
59382-59-1(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Description]
Methyl 2-methyl-3-nitrobenzoate(59382-59-1) is an important organic synthetic material and pharmaceutical intermediate compound. It can be used for the preparation of the anticancer drug lenalidomide as well as other organic compounds (e.g., indole-4-carboxylic acid methyl ester, 5-nitroisocoumarin, 5-aminoisoquinolin-1(2H)-one, etc.).
| [Chemical Properties]
White crystalline powder | [Uses]
Methyl 2-methyl-3-nitrobenzoate(59382-59-1) may be used in the synthesis of:
- methyl indole-4-carboxylate
- 5-aminoisoquinolin-1(2H)-one
- 5-nitroisocoumarin
- substituted nitrostyrene benzoic acids, via reaction with aromatic aldehydes in the presence of DBU in DMSO
- 4-(hydroxymethyl)-1-tosylindole, via Batcho-Leimgruber modification of the Reissert indole synthesis
- [2-(4-fluorophenyl)-1H-indol-4-yl]-1-pyrrolidinylmethanone
| [Uses]
Methyl 2-methyl-3-nitrobenzoate(59382-59-1) may be used in the synthesis of methyl indole-4-carboxylate, 5-aminoisoquinolin-1(2H)-one, 5-nitroisocoumarin and [2-(4-fluorophenyl)-1H-indol-4-yl]-1-pyrrolidinylmethanone. It may also be used in the preparation of substituted nitrostyrene benzoic acids, via reaction with aromatic aldehydes in the presence of DBU in DMSO; and 4-(hydroxymethyl)-1-tosylindole, via Batcho-Leimgruber modification of the Reissert indole synthesis.
| [Solubility in organics]
Soluble in methanol. |
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