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59609-49-3

59609-49-3 Structure

59609-49-3 Structure
IdentificationBack Directory
[Name]

ethyl 3-(2,2-dichlorovinyl)-2,2-dimethyl-1-cyclopropanecarboxylate
[CAS]

59609-49-3
[Synonyms]

Permethric acid ethyl ester
ethyl dichlorovinyl-2,2-dimethyl-1-cyclopropanecarboxylate
ETHYL 3-(2,2-DICHLOROVINYL)-2,2-DIME-1-CYCLOPROPANECARBOXYLATE
Ethyl 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
ethyl 3-(2,2-dichlorovinyl)-2,2-dimethyl-1-cyclopropanecarboxylate
2,2-Dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylic acid ethyl ester
ethyl(±)cis,trans-2,2-dimethyl-3-2,2-dichloro vinyl cyclopropane carboxylate
2-(2,2-Dichlorovinyl)-3,3-dimethylcyclopropane-1-carboxylic acid ethyl ester
Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-, ethyl ester
Ethyl 3-(2,2-dichlorovinyl)-2,2-dimethyl-1-cyclopropanecarboxylate,97%, mixture of cis and
[EINECS(EC#)]

261-826-7
[Molecular Formula]

C10H14Cl2O2
[MOL File]

59609-49-3.mol
[Molecular Weight]

237.123
Chemical PropertiesBack Directory
[Boiling point ]

338.48°C (rough estimate)
[density ]

1.2191 (rough estimate)
[refractive index ]

1.5410 (estimate)
[EPA Substance Registry System]

Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-, ethyl ester (59609-49-3)
Safety DataBack Directory
[Symbol(GHS) ]


GHS09
[Hazard statements ]

H411
Raw materials And Preparation ProductsBack Directory
[Raw materials]

p-Toluenesulfonic acid-->Sodium ethoxide-->Benzoyl peroxide-->Copper-->Isobutylene-->Chloral-->Gamma Butyrolactone-->16-Dehydropregnenolone acetate-->1-Hexene-->Methyl acetate-->3-Methyl-2-buten-1-ol-->diazoacetic acid-->orthoacetic acid-->2-METHYL-1-BUTENE-->Methylpentadiene
[Preparation Products]

Permethrin-->3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarbonyl chloride
Hazard InformationBack Directory
[Chemical Properties]

Ethyl permethrin is a colorless and transparent liquid, bp93~94℃/101pa, 78~88℃/27pa, n20D 1.4833, relative density 1.1170, insoluble In water, soluble in benzene, toluene, chloroform and other organic solvents.
[Uses]

Ethyl 3-(2,2-dichlorovinyl)-2,2-dimethyl-1-cyclopropanecarboxylate is an important intermediate of pyrethroids and can be used to prepare permethrin, cypermethrin, beta-cypermethrin, transfluthrin, cyfluthrin, etc.
[Synthesis]

Condensation of isobutylene and chloral under the catalysis of AlCl3 to form a enol, then acetylation, zinc powder reduction and acid-catalyzed isomerization to obtain conjugated dienes, and finally combined with diazoacetic acid Methyl ester (ethyl ester) reacts under the catalysis of copper powder to obtain ethyl 3-(2,2-dichlorovinyl)-2,2-dimethyl-1-cyclopropanecarboxylate.
Spectrum DetailBack Directory
[Spectrum Detail]

ethyl 3-(2,2-dichlorovinyl)-2,2-dimethyl-1-cyclopropanecarboxylate(59609-49-3)MS
ethyl 3-(2,2-dichlorovinyl)-2,2-dimethyl-1-cyclopropanecarboxylate(59609-49-3)13CNMR
ethyl 3-(2,2-dichlorovinyl)-2,2-dimethyl-1-cyclopropanecarboxylate(59609-49-3)IR1
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