| Identification | More | [Name]
Triphenylantimony | [CAS]
603-36-1 | [Synonyms]
ANTIMONY(III)TRIPHENYL
ANTIMONY TRIPHENYL
TRIPHENYLANTIMONY
TRIPHENYLANTIMONY(III)
TRIPHENYLSTIBINE
Trifenylstibin
Triphenylstibane
Triphenyl-stibane
triphenyl-stibin
Triphenylantimony,98%
Triphenylstilbine
Triphenylantimony,97%
Stibine, triphenyl-
Antimony(III)triphenyl, Triphenylstibine
Triphenylstiban
riphenylantimony | [EINECS(EC#)]
210-037-6 | [Molecular Formula]
C18H15Sb | [MDL Number]
MFCD00003000 | [Molecular Weight]
353.07 | [MOL File]
603-36-1.mol |
| Chemical Properties | Back Directory | [Appearance]
off-white powder | [Melting point ]
52-54 °C(lit.)
| [Boiling point ]
377 °C(lit.)
| [bulk density]
1490kg/m3 | [density ]
1,434 g/cm3 | [refractive index ]
1.6948 | [Fp ]
>230 °F
| [storage temp. ]
Store below +30°C. | [solubility ]
<0.001g/l | [form ]
crystal | [color ]
off-white | [Specific Gravity]
1.4343 | [Stability:]
Stable. Incompatible with strong oxidizing agents. | [Water Solubility ]
INSOLUBLE | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [BRN ]
3608108 | [InChI]
1S/3C6H5.Sb/c3*1-2-4-6-5-3-1;/h3*1-5H; | [InChIKey]
HVYVMSPIJIWUNA-UHFFFAOYSA-N | [SMILES]
c1ccc(cc1)[Sb](c2ccccc2)c3ccccc3 | [Uses]
Stibonium salts, cocatalyst in converting trienes
to aromatics and hydroaromatics, react with nitricsulfuric
acid to give trinitro derivatives, polymerization
inhibitor, lubricating-oil additive. | [CAS DataBase Reference]
603-36-1(CAS DataBase Reference) | [NIST Chemistry Reference]
Stibine, triphenyl-(603-36-1) | [EPA Substance Registry System]
603-36-1(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS06,GHS09 | [Signal word ]
Danger | [Hazard statements ]
H301-H332-H411 | [Precautionary statements ]
P261-P264-P270-P273-P301+P310-P304+P340+P312 | [Hazard Codes ]
Xn,N | [Risk Statements ]
R20/22:Harmful by inhalation and if swallowed .
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3467 6.1/PG 3
| [WGK Germany ]
2
| [RTECS ]
WJ1400000
| [TSCA ]
Yes | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [HS Code ]
29310095 | [Storage Class]
6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Oral
Acute Tox. 4 Inhalation
Aquatic Chronic 2 | [Safety Profile]
Poison by ingestion and
intraperitoneal routes. Flammable when
exposed to heat or flame. Can react
vigorously with oxidizing materials. To fight
fire, use water, foam, mist. When heated to
decomposition it emits toxic fumes of Sb.
See also ANTIMONY COMPOUNDS. |
| Hazard Information | Back Directory | [Chemical Properties]
off-white powder | [Reactions]
Under atmospheric conditions and at room temperature, a solution of furfuryl acetal (500 mg, 2.6 mmol) and triphenylantimony (92 mg, 0.3 mmol) in dichloromethane (10 mL) was stirred for 17 hours. The reaction mixture was concentrated under reduced pressure, and the crude product was purified by silica gel column chromatography (hexane: ethyl acetate = 3:1, Rf = 0.36) to afford a yellow solid, furfuryl acetic acid (466 mg, 94% yield).
Triphenylantimony dichloride was prepared by direct chlorination of triphenylantimony in petroleum ether or by reaction with aluminium trichloride (or iron(III) chloride) in chloroform. | [General Description]
Atomic number of base material: 51 Antimony | [reaction suitability]
core: antimony
reagent type: catalyst | [Purification Methods]
Recrystallise Ph3Sb from acetonitrile [Hayes et al. J Am Chem Soc 107 1346 1985]. [Beilstein 16 H 891, 16 IV 1198.] | [References]
[1] Yasuike, S., Kishi, Y., Kawara, S.-I., & Kurita, J. (2005). Catalytic action of triarylstibanes: oxidation of benzoins into benzyls using triarylstibanes under an aerobic condition. Chemical & Pharmaceutical Bulletin, 53 4, 425–427. https://doi.org/10.1248/cpb.53.425 |
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J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
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Energy Chemical
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400-0056266 |
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www.energy-chemical.com |
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Maya High Purity Chemicals
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+86 (573) 82222445 (0)18006601000 452520369 |
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www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm |
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