ChemicalBook--->CAS DataBase List--->6035-47-8

6035-47-8

6035-47-8 Structure

6035-47-8 Structure
IdentificationMore
[Name]

Sodium formaldehydesulfoxylate dihydrate
[CAS]

6035-47-8
[Synonyms]

FORMALDEHYDE SODIUM SULFOXYLATE
FORMALDEHYDE SULFOXYLATE SODIUM
FORMALDEHYDE SULFOXYLATE SODIUM DIHYDRATE
HYDROXYMETHANESULFINIC ACID, MONOSODIUM SALT DIHYDRATE
HYDROXYMETHANESULFINIC ACID SODIUM SALT
HYDROXYMETHANESULFINIC ACID SODIUM SALT DIHYDRATE
RONGALIT
RONGALITE
RONGALITE C
RONGALITE DIHYDRATE
RONGALITE(TM)
RONGALIT(R) DIHYDRATE
SODIUM FORMALDEHYDESULFOXALATE
SODIUM FORMALDEHYDE SULFOXYLATE
SODIUM FORMALDEHYDESULFOXYLATE DIHYDRATE
SODIUM HYDROXYMETHANESULFINATE
SODIUM HYDROXYMETHANESULFINATE DIHYDRATE
SODIUM HYDROXYMETHYLSULFINATE
SODIUM SULFOXYLATE FORMALDEHYDE
Methanesulfinicacid,hydroxy-,monosodiumsalt,dihydrate
[EINECS(EC#)]

205-739-4
[Molecular Formula]

CH6Na2O5S
[MDL Number]

MFCD00040426
[Molecular Weight]

176.1
[MOL File]

6035-47-8.mol
Chemical PropertiesBack Directory
[Appearance]

white crystalline powder
[Melting point ]

64-68 °C(lit.)
[bulk density]

950kg/m3
[density ]

1.8 g/cm3 (20℃)
[vapor pressure ]

2.68 hPa (20 °C)
[storage temp. ]

Store below +30°C.
[solubility ]

alcohol: slightly soluble(lit.)
[form ]

powder to crystal
[color ]

White to Almost white
[PH]

9.5-10.5 (100g/l, H2O, 20℃)
[Water Solubility ]

H2O: 50mg/mL, clear, colorless
[CAS DataBase Reference]

6035-47-8(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Health Hazard (GHS08)
GHS08
[Signal word ]

Warning
[Hazard statements ]

H341-H361d
[Precautionary statements ]

P201-P308+P313
[Hazard Codes ]

Xn
[Risk Statements ]

31-68
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[RTECS ]

PB0390000
[HS Code ]

28311000
[Toxicity]

LD50 orally in Rabbit: 6400 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

ZINC HYDROSULFITE
[Preparation Products]

microdispersoid acrylate resin filling emulsion-->Neoarsphenamine
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Sodium sulfinomethanolate dihydrate(6035-47-8).msds
Hazard InformationBack Directory
[Chemical Properties]

When freshly prepared, sodium formaldehyde sulfoxylate occurs as white, odorless crystals, which quickly develop a characteristic garlic odor on standing.
[Chemical Properties]

white crystalline powder
[Uses]

Sodium hydroxymethanesulfinate dihydrate is a versatile reagent that can be used for a wide range of organic transformations such as:
  • A SO2-2anion source for the preparation of sulfones and sultines.
  • Debromination of vicinal dibromoalkanes.
  • Reductive dehalogenation of aldehydes and ketones.

[Uses]

Pharmaceutic aid (preservative).
[Production Methods]

Sodium formaldehyde sulfoxylate is manufactured from sodium dithionate and formaldehyde in water.
[General Description]

Oxidation reation of hydroxymethanesulfinic acid with chlorite has been studied in the pH range 4-8. It is a sulfur-containing reducing agent.
[Pharmaceutical Applications]

Sodium formaldehyde sulfoxylate is a water-soluble antioxidant and is generally used as the dihydrate. It is used in the formulation of injection products at a level of up to 0.1% w/v in the final preparation administered to the patient.
[Safety]

The toxicological properties of sodium formaldehyde sulfoxylate have not been fully investigated. However, it is used in the formulation of injection products at a level to 0.1% w/v in the final preparation administered to the patient.
Sodium formaldehyde sulfoxylate is moderately toxic by ingestion, and when heated to decomposition it emits toxic fumes of sulfur dioxide and sodium oxide.
LD50 (mouse, oral): 4 g/kg
LD50 (rat, IP): >2 g/kg
LD50 (rat, oral): >2 g/kg
[storage]

Store in well-closed, light-resistant containers at controlled room temperature (15–30℃).
[Incompatibilities]

Sodium formaldehyde sulfoxylate is incompatible with strong oxidizing agents; it is decomposed by dilute acid.
[Regulatory Status]

Included in the FDA Inactive Ingredients Database (parenteral products up to 0.1% via the IM, IV, and SC routes). Included in the Canadian List of Acceptable Non-medicinal Ingredients.
Spectrum DetailBack Directory
[Spectrum Detail]

Sodium formaldehydesulfoxylate dihydrate(6035-47-8)1HNMR
Sodium formaldehydesulfoxylate dihydrate(6035-47-8)Raman
Sodium formaldehydesulfoxylate dihydrate(6035-47-8)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Sodium formaldehydesulfoxylate dihydrate, 98%(6035-47-8)
[Sigma Aldrich]

6035-47-8(sigmaaldrich)
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