| Identification | More | [Name]
Methyl 2-benzoylbenzoate | [CAS]
606-28-0 | [Synonyms]
2-BENZOYLBENZOIC ACID METHYL ESTER
BENZOPHENONE-2-CARBOXYLIC ACID METHYL ESTER
METHYL 2-BENZOYLBENZOATE
METHYL BENZOPHENONE-2-CARBOXYLATE
METHYL O-BENZOYLBENZOATE
METHYL O-BENZOYLE BENZOATE
O-BENZOYLBENZOIC ACID METHYL ESTER
O-BENZOYL BENZOMETHOXYCARBONYL
OBM
2-benzoyl-benzoicacimethylester
Benzoic acid, o-benzoyl-, methyl ester
o-(Methoxycarbonyl)benzophenone
OMBB
2-Methylbenzoyl benzoate
PHOTOCURE 55
O-BENZOYL BENZOMETHOXYCARBONYL(OBM)
Methyl0-BenzoylBenzoate
Benzoic acid, 2-benzoyl-, methyl ester
METHYLORTHO-BENZOYLBENZOATE
Methyo-benzoylbenzoate | [EINECS(EC#)]
210-112-3 | [Molecular Formula]
C15H12O3 | [MDL Number]
MFCD00017187 | [Molecular Weight]
240.25 | [MOL File]
606-28-0.mol |
| Chemical Properties | Back Directory | [Melting point ]
48-53 °C (lit.) | [Boiling point ]
352 °C | [density ]
1,69 g/cm3 | [vapor pressure ]
0Pa at 20℃ | [refractive index ]
1.5740 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Insoluble in water | [form ]
powder to crystal | [color ]
White to Orange to Green | [Water Solubility ]
117.7mg/L at 20℃ | [InChI]
1S/C15H12O3/c1-18-15(17)13-10-6-5-9-12(13)14(16)11-7-3-2-4-8-11/h2-10H,1H3 | [InChIKey]
NQSMEZJWJJVYOI-UHFFFAOYSA-N | [SMILES]
COC(=O)c1ccccc1C(=O)c2ccccc2 | [LogP]
2.8 at 25℃ | [CAS DataBase Reference]
606-28-0(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzoic acid, 2-benzoyl-, methyl ester(606-28-0) | [EPA Substance Registry System]
606-28-0(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS09 | [Signal word ]
Warning | [Hazard statements ]
H410 | [Precautionary statements ]
P273-P391-P501 | [Hazard Codes ]
N | [Risk Statements ]
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3077 9/PG 3
| [WGK Germany ]
3
| [TSCA ]
TSCA listed | [REACH Registrations]
Active | [HazardClass ]
9 | [HS Code ]
29183000 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Aquatic Acute 1
Aquatic Chronic 1 |
| Hazard Information | Back Directory | [Chemical Properties]
White or yellowish granule crystals, soluble in alcohol and alkali solution, almost insoluble in water when precipitated in acid. | [Uses]
Methyl 2-benzoylbenzoate is used as an anti-ultraviolet absorber and a preservative for food and beverages. | [Definition]
ChEBI: Methyl 2-benzoylbenzoate is a member of benzophenones. | [Preparation]
Methyl-2-benzoylbenzoate can be synthesized from the reaction between corresponding 2-substituted benzoic acid and thionyl chloride in methanol. | [General Description]
Methyl-2-benzoylbenzoate is a 2-acylarylcarboxylate.
- It can undergo asymmetric transfer hydrogenation reaction in propanol in the presence of a Ruthenium catalyst.
- Methyl-2-benzoylbenzoate is formed as one of the reaction products during the reaction between methyl benzoate and lithium 2,2,6,6-tetramethylpiperidide (LiTMP) at -117°C.
- Methyl-2-benzoylbenzoate can be synthesized from the reaction between corresponding 2-substituted benzoic acid and thionyl chloride in methanol.
| [Flammability and Explosibility]
Nonflammable |
|
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