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103-26-4

103-26-4 Structure

103-26-4 Structure
IdentificationMore
[Name]

Methyl cinnamate
[CAS]

103-26-4
[Synonyms]

CINNAMIC ACID METHYL ESTER
FEMA 2698
METHYL 3-PHENYLACRYLATE
METHYL-3-PHENYL PROP-2-ENOATE
METHYL 3-PHENYLPROPENOATE
METHYL-3-PHENYLPROPENOTE
METHYL CINNAMATE
METHYL CINNAMYLATE
METHYL TRANS-3-PHENYLACRYLATE
METHYL TRANS-3-PHENYLPROPENOATE
METHYL TRANS-CINNAMATE
TRANS-3-PHENYLACRYLIC ACID METHYL ESTER
2-Propenoicacid,3-phenyl-,methylester
3-phenyl-2-propenoicacimethylester
3-phenyl-prop-2-enoicacidmethylester
Methyl 3-phenyl-2-propenoate
Methyl ester of Cinnamic acid
methyl3-phenyl-2-propenoate
methl β-phenylacrylate
METHYL CINNAMATE 99%
[EINECS(EC#)]

203-093-8
[Molecular Formula]

C10H10O2
[MDL Number]

MFCD00008458
[Molecular Weight]

162.19
[MOL File]

103-26-4.mol
Chemical PropertiesBack Directory
[Appearance]

White to light yellow fused crystalline mas
[mp ]

34-38 °C(lit.)
[bp ]

260-262 °C(lit.)
[density ]

1.092
[refractive index ]

1.5771
[FEMA ]

2698
[Fp ]

>230 °F
[Water Solubility ]

insoluble
[Detection Methods]

GC
[Merck ]

14,2299
[BRN ]

386468
[Uses]

Perfumes, flavoring.
[CAS DataBase Reference]

103-26-4(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Propenoic acid, 3-phenyl-, methyl ester(103-26-4)
[EPA Substance Registry System]

103-26-4(EPA Substance)
Safety DataBack Directory
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

1
[RTECS ]

GE0190000
[HS Code ]

29163990
[Safety Profile]

Moderately toxic by ingestion. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

trans-Cinnamic acid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

3-Phenyl-2-propenoic acid methyl ester(103-26-4).msds
Questions And AnswerBack Directory
[Chemical Properties]

It appears as white to slightly yellow crystal with cherry and fragrant ester fragrant {gas. It has a melting point of 34 ° C, a boiling point of 260 ° C, a refractive index (nD20) of 1.5670 and relative density (d435) of 1.0700. It is soluble in ethanol, ether, glycerol, propylene glycol. It mostly exists in non-volatile oil and mineral oil, insoluble in water.
Natural products are contained in basil oil (up to 52%), galangal oil and cinnamon oil.
[Preparative Methods]

It is obtained by esterification of cinnamic acid with methanol. The mixture of cinnamic acid, methanol and sulfuric acid (or hydrochloric acid) was heated to reflux for 5 h, and the excess amount of methanol was added. Cool and spate the acid layer, washed with water and 10% sodium carbonate solution, and then washed with water to neutral. The crude product was subjected to recrystallization or vacuum distillation [collection of 132-134 ° C (2.0 kPa) fraction] to give methyl cinnamate with a yield of about 70%.
Spectrum DetailBack Directory
[Spectrum Detail]

Methyl cinnamate(103-26-4)1HNMR
Methyl cinnamate(103-26-4)MS
Methyl cinnamate(103-26-4)Raman
Methyl cinnamate(103-26-4)IR1
Methyl cinnamate(103-26-4)IR3
Methyl cinnamate(103-26-4)13CNMR
Methyl cinnamate(103-26-4)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Methyl cinnamate, 98%(103-26-4)
[Alfa Aesar]

Methyl cinnamate, predominantly trans, 99%(103-26-4)
[Sigma Aldrich]

103-26-4(sigmaaldrich)
[TCI AMERICA]

Methyl Cinnamate,>99.0%(GC)(103-26-4)
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