| Identification | More | [Name]
2-Nitrophenylacetonitrile | [CAS]
610-66-2 | [Synonyms]
2-NITROBENZYL CYANIDE
2-NITROPHENYLACETONITRILE
O-NITROBENZYL CYANIDE
(o-nitrophenyl)-acetonitril
2-nitro-benzeneacetonitril
2-nitrobenzeneacetonitrile
2-nitrobenzylnitrile
o-nitrobenzacetonitrile
2-Nitrophenylacetonitrile,98%
2-Nitrophenylacetonitrile 98%
ORTHO-NITROPHENYLACETONITRILE
2-(2-Nitrophenyl)acetonitrile
o-Nitro-α-toluic nitrile | [EINECS(EC#)]
210-231-0 | [Molecular Formula]
C8H6N2O2 | [MDL Number]
MFCD00007183 | [Molecular Weight]
162.15 | [MOL File]
610-66-2.mol |
| Chemical Properties | Back Directory | [Appearance]
Yellow Solid | [Melting point ]
82-85 °C(lit.) | [Boiling point ]
178°C | [density ]
1.3264 (rough estimate) | [refractive index ]
1.5770 (estimate) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Chloroform, Ethyl Acetate | [form ]
Powder | [color ]
Light brown to brownish-gray | [Stability:]
Stable. Incompatible with strong oxidizing agents. | [Water Solubility ]
<0.01 g/100 mL at 20 ºC | [BRN ]
1869400 | [Exposure limits]
NIOSH: IDLH 25 mg/m3 | [InChI]
1S/C8H6N2O2/c9-6-5-7-3-1-2-4-8(7)10(11)12/h1-4H,5H2 | [InChIKey]
YPRFCQAWSNWRLM-UHFFFAOYSA-N | [SMILES]
[O-][N+](=O)c1ccccc1CC#N | [CAS DataBase Reference]
610-66-2(CAS DataBase Reference) | [EPA Substance Registry System]
610-66-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes . | [RIDADR ]
3439 | [WGK Germany ]
3
| [RTECS ]
AM1248000
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29269090 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [General Description]
Light brown solid. | [Reactivity Profile]
Nitriles, such as O-NITROPHENYLACETONITRILE(610-66-2), may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids. | [Air & Water Reactions]
Insoluble in water. | [Fire Hazard]
Flash point data for this chemical are not available. O-NITROPHENYLACETONITRILE is probably combustible. | [Chemical Properties]
Yellow Solid | [Uses]
2-Nitrophenylacetonitrile was used in synthesis of 2 or 2,4-substituted α-carbolines via a one-pot tandem reaction of α,β-unsaturated ketones. It was used in the synthesis of strychnine. | [Synthesis Reference(s)]
Synthesis, p. 514, 1987 DOI: 10.1055/s-1987-27989 |
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| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
China Langchem Inc.
|
| Telephone: |
0086-21-58956006 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm |
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